Question 30.7: An exoergic reaction Now let’s use Equation 30.12 to calcula...
An exoergic reaction
Now let’s use Equation 30.12 to calculate the reaction energy when lithium is bombarded by a proton and two alpha particles are produced.
\mathrm{Q = (M_A+M_B-M_C-M_D)}c^2. (30.12)
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SET UP The reaction can be represented as
\mathrm{^1_1 H + ^7_3Li \rightarrow {}^4_2He + ^4_2He.}
We need to use the definition of reaction energy, Equation 30.12. The masses we need are given in Table 30.2.
SOLVE From Table 30.2, we find the initial and final masses:
\mathrm{\begin{matrix} A: {}^1_1H & 1.007825 u & C:^4_2He& 4.002603 u \end{matrix} }
\mathrm{\begin{matrix} B: {^7_3Li} &\frac{7.016005 u}{8.023830 u} & D: {}^4_2He &\frac{4.002603 u}{8.005206 u} \end{matrix} }
Four electron masses are included on each side. We see that
\mathrm{M_A + M_B – M_C – M_D = 0.018624 u.}
The mass decreases by 0.018624 u; from Equation 30.12, the reaction energy is
\mathrm{Q = (M_A+M_B-M_C-M_D)}c^2. (30.12)
Q = (0.018624 u)(931.5 MeV/u) = 17.35 MeV.
REFLECT The total mass decreases, so the total kinetic energy increases. The final total kinetic energy of the two separating α particles is 17.35 MeV greater than the initial total kinetic energy of the proton and the lithium nucleus.
Practice Problem: Find the Q value for the reaction \mathrm{^1_0n + ^{10}_5B \rightarrow ^7_3Li + ^4_2He.} Is this reaction exoergic or endoergic? Answers: 2.79 MeV, exoergic.
TABLE 30.2 Atomic masses of light elements | ||||
Element | Atomic number, Z |
Mass number, N |
Atomic mass u |
Mass number, A |
Hydrogen, H | 1 | 0 | 1.007825 | 1 |
Deuterium, H | 1 | 1 | 2.014101 | 2 |
Helium, He | 2 | 1 | 3.016029 | 3 |
Helium, He | 2 | 2 | 4.002603 | 4 |
Lithium, Li | 3 | 3 | 6.015123 | 6 |
Lithium, Li | 3 | 4 | 7.016003 | 7 |
Beryllium, Be | 4 | 5 | 9.012183 | 9 |
Boron, B | 5 | 5 | 10.012937 | 10 |
Boron, B | 5 | 6 | 11.009305 | 11 |
Carbon, C | 6 | 6 | 12.000000 | 12 |
Carbon, C | 6 | 7 | 13.003355 | 13 |
Nitrogen, N | 7 | 7 | 14.003074 | 14 |
Nitrogen, N | 7 | 8 | 15.000109 | 15 |
Oxygen, O | 8 | 8 | 15.994915 | 16 |
Oxygen, O | 8 | 9 | 16.999132 | 17 |
Oxygen, O | 8 | 10 | 17.999160 | 18 |
Source: Atomic Mass Evaluation 2013. M. Wang et al 2012 Chinese Phys. C 36 1603 doi:10.1088/1674-1137/36/12/003 |