Question 25.2: Writing Electron Configurations for Transition Metals Write ...

Writing Electron Configurations for Transition Metals

Write the ground state electron configuration for Co^{3+}.

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Writing Electron Configurations
Identify the noble gas that precedes the element and write it in square brackets.  

[Ar]

Count down the periods to determine the outer principal quantum level—this is the quantum level for the s orbital.

Subtract one to obtain the quantum level for the d orbital. If the element is in the third or fourth transition series, include (n – 2)f^{14} electrons in the configuration.

Co is in the fourth period, so the orbitals used are:

[Ar] 4s3d

Count across the row to see how many electrons are in the neutral atom and fill the orbitals accordingly. Co has nine more electrons than Ar.

[Ar] 4s^23d^7

For an ion, remove the required number of electrons, first from the s and then from the d orbitals. Co^{3+} has three fewer electrons than the Co atom.

[Ar]  4s^03d^6  or  [Ar]  3d^6

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