Question 25.9: High- and Low-Spin Octahedral Complexes How many unpaired el...

High- and Low-Spin Octahedral Complexes

How many unpaired electrons are there in the complex ion [CoF_6]^{3-}?

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Determining the Number of Unpaired Electrons in Octahedral Complexes
Begin by determining the charge and number of d electrons on the metal. SOLUTION

The metal is Co^{3+} and has a d^{6} electronic configuration.

Look at the spectrochemical series to determine whether the ligand is a strong-field or a weak-field ligand. F^{-} is a weak-field ligand, so Δ is relatively small.
Decide if the complex is high- or low-spin and draw the electron configuration. Weak-field ligands yield high-spin configurations.

Count the unpaired electrons. This configuration has four unpaired electrons.

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