Question 22.6: Identifying and Drawing Geometric Isomers Draw the structur...
Identifying and Drawing Geometric Isomers
Draw the structures and label the type for all the isomers of [Ni(CN)_2Cl_2]^{2-}.
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Identify the coordination number and the geometry around the metal.
All the ligands are monodentate, so the total coordination number is 4. Ni^{2+} is a d^8 electronic configuration, so we expect a square planar complex.
Identify whether this is a cis–trans or fac–mer isomerism.
Square planar complexes can only have cis–trans isomers.
Draw and label the two isomers.
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