In the crystallizer of Example 27.5, a growth rate G of 0.0018 ft/h (0.00055 m/h) is anticipated, and a predominant crystal size of 20 mesh is desired. How large must the magma volume in the crystallizer be; what nucleation rate B° is necessary; and what is the screen analysis of the product, assuming that the operation conforms to all the requirements of the mixed suspension-mixed product crystallization?
The screen opening of a 20-mesh standard screen is, from Appendix 20, 0.0328 in., or 0.00273 ft. This dimension can be used for L, and the shape factor a [Eq. (27.16)] is assumed to be unity. From Example 27.5, the volume flow rate of mother liquor in the product magma is
vp=aL3 (27.16)
Q=82.544,520=540 ft3/h
Since, when z = 3, Lpr = 0.00273, Eq. (27.28) gives for the drawdown time and the volume of liquid in the crystallizer
z≡GτL (27.28)
τ=3GLpr=3×0.00180.00273=0.506 hVc=0.506×540=273 ft3
The total magma volume is 273/0.85 = 321 ft³, or 2400 gal.
The nucleation rate is, from Eq. (27.44), since C = 10,000 lb/h,
B∘=mcVcCnc=6aρc(Gτ)3VcC=2aρcVcLpr39C (27.44)
B∘=2×105×273×0.0027339×10,000=7.72×109 nuclei /t3−h(2.74×109 nuclei /m3−h)
By Eq. (27.40), the zero-size particle density is n° = 7.72 × 107/0.0018 = 4.289 × 1010 nuclei/ft4 The value of L/Gτ is L/(0.0018)(0.506) = 1.1 × 10³ L. The equation for the number-density distribution is, from Eq. (27.27),
B∘=Gn∘ (27.40)
∫n∘nndn=−Gτ1∫0LdLlnnn∘=GτL (27.27)
logn=logn∘−2.30261.1×103L=10.632−4.777×102L
This equation is plotted in Fig. 27.16.
The screen analysis is found by reading ordinates from Fig. 27.15c for values of z corresponding to mesh openings. For example, for the 20-mesh point, where z = 3, xm is 0.35. In general,
z=τGL=0.506×0.0018L=1098L
Details are given in Table 27.2.
TABLE 27.2 | |||||
Mesh | Size | z | Screen analysis, % | ||
ft | mm | Cumulative | Differential | ||
8 | 0.0078 | 2.37 | 8.5 | 97 | 3 |
9 | 0.0065 | 1.98 | 7.1 | 93 | 4 |
10 | 0.0054 | 1.65 | 5.9 | 84 | 9 |
12 | 0.0046 | 1.40 | 5 | 74 | 10 |
14 | 0.0038 | 1.16 | 4.2 | 61 | 13 |
16 | 0.0033 | 1.01 | 3.6 | 48 | 13 |
20 | 0.0027 | 0.82 | 3.0 | 35 | 13 |
24 | 0.0023 | 0.70 | 2.5 | 25 | 10 |
28 | 0.0019 | 0.58 | 2.1 | 17 | 8 |
32 | 0.0016 | 0.49 | 1.8 | 11 | 6 |
35 | 0.0014 | 0.43 | 1.5 | 6 | 5 |
42 | 0.0011 | 0.34 | 1.2 | 4 | 2 |