Estimate c_p, the molar heat capacity of the iron silicon spinel, Fe_2SiO_4, at very high temperatures (> 1400 K).
Estimate c_p, the molar heat capacity of the iron silicon spinel, Fe_2SiO_4, at very high temperatures (> 1400 K).
Assume that this is in the range where the Dulong and Petit law is followed. There are seven atoms in the formula unit of the spinel. Thus, by Kopp’ s rule, we estimate c_v to be 7 × 3R = 21R = 174.6 J/mole.K; c_p would be larger than that number.
Actual c_p at 1400 K = 206 J/mole.K.