Find the expectation value of the potential energy in the nth stationary state of the harmonic oscillator.
Find the expectation value of the potential energy in the nth stationary state of the harmonic oscillator.
\left\langle V\right\rangle =\left\langle\frac{1}{2}m\omega ^{2}x^{2} \right\rangle =\frac{1}{2}m \omega ^{2}\int_{-\infty }^{\infty }{\psi ^{*}_{n}} x^{2} \psi _{n}dx
There’s a beautiful device for evaluating integrals of this kind (involving powers of x or \hat{p} : Use the definition (Equation 2.48) [\hat{a} _{\pm}\equiv \frac{1}{\sqrt{2\hbar m\omega } } (\mp i\hat{p}+m\omega x )] to express x and in terms of the raising and lowering operators:
x=\sqrt{\frac{\hbar }{2m \omega } }(\hat{a} _{+}+\hat{a} _{-}) ;\hat{p}=i\sqrt{\frac{\hbar m\omega }{2} } (\hat{a} _{+}-\hat{a} _{-}) (2.70)
In this example we are interested in x^{2} :
x^{2}=\frac{\hbar }{2m \omega }\left[(\hat{a} _{+})^{2}+(\hat{a} _{+}\hat{a} _{-})+(\hat{a} _{-}\hat{a} _{+})+(\hat{a} _{-})^{2}\right]
So
\left\langle V\right\rangle =\frac{\hbar \omega }{4}\int_{-\infty }^{\infty }{\psi ^{*}_{n}} \left[( \hat {a} _{+})^{2}+(\hat{a} _{+}\hat{a} _{-})+(\hat{a} _{-}\hat{a} _{+})+(\hat{a} _{-} )^{2}\right] \psi _{n}dx
But (\hat{a} _{+})^{2}\psi _{n} is (apart from normalization) \psi _{n+2} , which is orthogonal to \psi _{n} , and the same goes for (\hat{a} _{-})^{2}\psi _{n}, which is proportional to \psi _{n-2} . So those terms drop out, and we can use Equation 2.66 [\hat{a} _{+}\hat{a} _{-}\psi _{n}=n\psi _{n},\hat{a} _{-}\hat{a} _{+}\psi _{n}=(n+1)\psi _{n}] to evaluate the remaining two:
\left\langle V\right\rangle =\frac{\hbar \omega }{4}(n+n+1)=\frac{1}{2} \hbar \omega\left(n+\frac{1}{2} \right)
As it happens, the expectation value of the potential energy is exactly half the total (the other half, of course, is kinetic). This is a peculiarity of the harmonic oscillator, as we’ll see later on (Problem 3.37).