Question 2.1: Prove the following three theorems: (a) For normalizable sol...

2.1 Prove the following three theorems:

(a) For normalizable solutions, the separation constant E must be real. Hint: Write E (in Equation 2.7) as E0+iΓ E_0 + iΓ (with E0 and Γ real), and show that if Equation 1.20 is to hold for all t, Γ must be zero.

Ψ(x,t)=ψ(x)eiEt/ \Psi(x, t)=\psi(x) e^{-i E t / \hbar}         (2.7).

+Ψ(x,t)2dx=1 \int_{-\infty}^{+\infty}|\Psi(x, t)|^{2} d x=1         (1.20).

(b) The time-independent wave function ψ(x) can always be taken to be real (unlike Ψ (x,t) , which is necessarily complex). This doesn’t mean that every solution to the time-independent Schrödinger equation is real; what it says is that if you’ve got one that is not, it can always be expressed as a linear combination of solutions (with the same energy) that are. So you might as well stick to s that are real. Hint: If ψ(x) satisfies Equation 2.5, for a given E, so too does its complex conjugate, and hence also the real linear combinations (ψ+ψ) (ψ + ψ^*) and i(ψψ) i (ψ - ψ^*) .

h22md2ψdx2+Vψ=Eψ -\frac{h^{2}}{2 m} \frac{d^{2} \psi}{d x^{2}}+V \psi=E \psi       (2.5).

(c) If V(x) is an even function (that is, V(-x) = V(x)) then ψ(x) can always be taken to be either even or odd. Hint: If ψ(x) satisfies Equation  2.5, for a given E, so too does ψ(- x),  and hence also the even and odd linear combinations ψ(x) ±ψ(- x).

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(a)

Ψ(x,t)=ψ(x)ei(E0+iΓ)t/=ψ(x)eΓt/eiE0t/Ψ2=ψ2e2Γt/ \Psi(x, t)=\psi(x) e^{-i\left(E_{0}+i \Gamma\right) t / \hbar}=\psi(x) e^{\Gamma t / \hbar} e^{-i E_{0} t / \hbar} \Longrightarrow|\Psi|^{2}=|\psi|^{2} e^{2 \Gamma t / \hbar} .

Ψ(x,t)2dx=e2Γt/ψ2dx \int_{-\infty}^{\infty}|\Psi(x, t)|^{2} d x=e^{2 \Gamma t / \hbar} \int_{-\infty}^{\infty}|\psi|^{2} d x .

The second term is independent of t, so if the product is to be 1 for all time, the first term (e2Γt/) (e^{2Γt/\hbar}) must also be constant, and hence Γ = 0.     QED.

(b) If ψ satisfies Eq. 2.5

h22md2ψdx2+Vψ=Eψ -\frac{h^{2}}{2 m} \frac{d^{2} \psi}{d x^{2}}+V \psi=E \psi       (2.5).

then (taking the complex conjugate and noting that V and E are real): h22md2ψdx2+Vψ=Eψ -\frac{h^{2}}{2 m} \frac{d^{2} \psi^*}{d x^{2}}+V \psi^*=E \psi^* , so ψ \psi^* also satisfies Eq. 2.5. Now, if ψ1 ψ_1 satisfy Eq. 2.5, so too does any linear combination of them (ψ3c1ψ1+c2ψ2 ψ_3 ≡ c_1 ψ_1 + c_2 ψ_2 ):

h22md2ψdx2+Vψ=Eψ -\frac{h^{2}}{2 m} \frac{d^{2} \psi}{d x^{2}}+V \psi=E \psi       (2.5).

22md2ψ3dx2+Vψ3=22m(c1d2ψ1dx2+c2d2ψ2dx2)+V(c1ψ1+c2ψ2) -\frac{\hbar^{2}}{2 m} \frac{d^{2} \psi_{3}}{d x^{2}}+V \psi_{3}=-\frac{\hbar^{2}}{2 m}\left(c_{1} \frac{d^{2} \psi_{1}}{d x^{2}}+c_{2} \frac{d^{2} \psi_{2}}{d x^{2}}\right)+V\left(c_{1} \psi_{1}+c_{2} \psi_{2}\right) =c1[22md2ψ1dx2+Vψ1]+c2[22md2ψ2dx2+Vψ2] =c_{1}\left[-\frac{\hbar^{2}}{2 m} \frac{d^{2} \psi_{1}}{d x^{2}}+V \psi_{1}\right]+c_{2}\left[-\frac{\hbar^{2}}{2 m} \frac{d^{2} \psi_{2}}{d x^{2}}+V \psi_{2}\right]

=c1(Eψ1)+c2(Eψ2)=E(c1ψ1+c2ψ2)=Eψ3 =c_{1}\left(E \psi_{1}\right)+c_{2}\left(E \psi_{2}\right)=E\left(c_{1} \psi_{1}+c_{2} \psi_{2}\right)=E \psi_{3} .

Thus, (ψ+ψ) (ψ + ψ^*) and i(ψψ) i (ψ – ψ^*) – both of which are real – satisfy Eq. 2.5. Conclusion: From any complex solution, we can always construct two real solutions (of course, if ψ is already real, the second one will be zero). In particular, since ψ=12[(ψ+ψ)i(i(ψψ))] \psi=\frac{1}{2}\left[\left(\psi+\psi^{*}\right)-i\left(i\left(\psi-\psi^{*}\right)\right)\right] , ψ can be expressed as a linear combination of two real solutions.     QED.

(c) If ψ(x) satisfies Eq. 2.5, then, changing variables x → -x and noting that d²/d(-x)² = d² /dx²,

h22md2ψdx2+Vψ=Eψ -\frac{h^{2}}{2 m} \frac{d^{2} \psi}{d x^{2}}+V \psi=E \psi       (2.5).

22md2ψ(x)dx2+V(x)ψ(x)=Eψ(x) -\frac{\hbar^{2}}{2 m} \frac{d^{2} \psi(-x)}{d x^{2}}+V(-x) \psi(-x)=E \psi(-x) ;

so if V (-x) = V (x) then ψ(-x) also satisfies Eq. 2.5. It follows that ψ+(x)ψ(x)+ψ(x) ψ_+(x) ≡ ψ(x) + ψ(-x) (which is even: ψ+(x)=ψ+(x) ψ_+(-x) = ψ_+(x) ) and ψ(x)ψ(x)ψ(x) ψ_-(x) ≡ ψ(x) – ψ(-x) (which is odd: ψ(x)=ψ(x)  ψ_-(x) = -ψ_-(x)  ) both satisfy Eq.2.5. But ψ(x)=12(ψ+(x)+ψ(x)) \psi(x)=\frac{1}{2}\left(\psi_{+}(x)+\psi_{-}(x)\right) , so any solution can be expressed as a linear combination of even and odd solutions.    QED.

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