Although the overall phase constant of the wave function is of no physical significance (it cancels out whenever you calculate a measurable quantity), the relative phase of the coefficients in Equation 2.17 does matter. For example, suppose we change the relative phase of and in Problem 2.5:
\Psi(x, t)=\sum_{n=1}^{\infty} c_{n} \psi_{n}(x) e^{-i E_{n} t / \hbar}=\sum_{n=1}^{\infty} c_{u} \Psi_{n}(x, t) (2.17).
\Psi(x, 0)=A\left[\psi_{1}(x)+e^{i \phi} \psi_{2}(x)\right] ,
where ϕ is some constant. Find Ψ(x,t) , \left|Ψ(x,t) \right| ^2 and \left\langle x\right\rangle and compare your results with what you got before. Study the special cases ϕ = 2 π and ϕ = π. (For a graphical exploration of this problem see the applet in footnote 9 of this chapter.)