Question 2.6: Although the overall phase constant of the wave function is ...

Although the overall phase constant of the wave function is of no physical significance (it cancels out whenever you calculate a measurable quantity), the relative phase of the coefficients in Equation 2.17 does matter. For example, suppose we change the relative phase of and in Problem 2.5:

\Psi(x, t)=\sum_{n=1}^{\infty} c_{n} \psi_{n}(x) e^{-i E_{n} t / \hbar}=\sum_{n=1}^{\infty} c_{u} \Psi_{n}(x, t)         (2.17).

\Psi(x, 0)=A\left[\psi_{1}(x)+e^{i \phi} \psi_{2}(x)\right] ,

where ϕ is some constant. Find Ψ(x,t) , \left|Ψ(x,t) \right| ^2 and \left\langle x\right\rangle and compare your results with what you got before. Study the special cases ϕ = 2 π and ϕ =  π. (For a graphical exploration of this problem see the applet in footnote 9 of this chapter.)

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From Problem 2.5, we see that

Ψ(x,t) = \frac{1}{\sqrt{a}} e^{-i \omega t}\left[\sin \left(\frac{\pi}{a} x\right)+\sin \left(\frac{2 \pi}{a} x\right) e^{-3 i \omega t} e^{i \phi}\right] .

\left|Ψ(x,t) \right| ^2 = \frac{1}{a}\left[\sin ^{2}\left(\frac{\pi}{a} x\right)+\sin ^{2}\left(\frac{2 \pi}{a} x\right)+2 \sin \left(\frac{\pi}{a} x\right) \sin \left(\frac{2 \pi}{a} x\right) \cos (3 \omega t-\phi)\right] .

and hence \langle x\rangle=\frac{a}{2}\left[1-\frac{32}{9 \pi^{2}} \cos (3 \omega t-\phi)\right] .

This amounts physically to starting the clock at a different time (i.e., shifting the t = 0 point).

If ϕ = \frac{π}{2} , so \Psi(x, 0)=A\left[\psi_{1}(x)+i \psi_{2}(x)\right] , then \cos (3 \omega t-\phi)=\sin (3 \omega t) ; \left\langle x\right\rangle starts at \frac{a}{2} .

If ϕ = π, so \Psi(x, 0)=A\left[\psi_{1}(x)-\psi_{2}(x)\right] , then \cos (3 \omega t-\phi)=-\cos (3 \omega t) \left\langle x\right\rangle starts at \frac{a}{2}\left(1+\frac{32}{9 \pi^{2}}\right) .

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