Question 4.12: Stoichiometry . When urea, (NH)2 2CO, is acted on by the enz...

Stoichiometry . When urea, (NH_{2})_{2} CO , is acted on by the enzyme urease in the presence of water, ammonia and carbon dioxide are produced. Urease, the catalyst, is placed over the reaction arrow.

Stoichiometry . When urea, (NH)2 2CO, is acted on by the enzyme urease in the presence of water, ammonia and carbon dioxide are produced. Urease, the catalyst, is placed over the reaction arrow.If excess water is present (more than necessary for the reaction), how many grams each of CO2 and NH3

If excess water is present (more than necessary for the reaction), how
many grams each of CO_{2}  and   NH_{3} are produced from 0.83 mol of urea?

Strategy : We are given moles of urea and asked for grams of CO_{2}. First, we use the conversion factor 1 mol urea = 1 mol CO_{2} to find the number of moles of CO_{2} that will be produced and then convert moles of CO_{2} to grams of CO_{2}. We use the same strategy to find the number of grams of NH_{3} produced.

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For grams of CO_{2}:

Step 1: We first convert moles of urea to moles of carbon dioxide, using the conversion factor derived from the balanced chemical equation, 1 mol urea = 1 mol carbon dioxide.

0.83 \cancel{mol  urea} \times \frac{1 mol CO_{2} }{1 \cancel{mol  urea} } = mol CO_{2}

Step 2: Use the conversion factor 1 mol CO_{2} = 44 g CO_{2} and then do the math to give the answer:

0.83 \cancel{mol  urea} \times \frac{1 \cancel{mol  CO_{2}} }{1 \cancel{mol  urea} }\times \frac{44 g CO_{2} }{1\cancel{mol  CO_{2}} } =37 g CO_{2}

For grams of NH_{3} :

Steps 1 and 2 combined into one equation: We follow the same procedure as for CO_{2}but use different conversion factors:

0.83 \cancel{mol  urea} \times \frac{2 \cancel{mol  NH_{3}} }{1 \cancel{mol  urea} }\times \frac{17  g  NH_{3} }{1\cancel{mol  NH_{3}} } =28 g NH_{3}

 

 

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