Question 8.1: Consider a ceramic package where the solder glass used has t...

Consider a ceramic package where the solder glass used has the following properties; E(g) = 0.7 × 10^6 kg/cm^2 , v(g) = 0.27, α(g) = 6.8 × 10^{-6} °C^{-1}. Similarly, for the alumina ceramic, E(c) = 3.5 × 10^6 kg/cm^2 , v(c) = 0.25, α(c) = 7.2 × 10^{-6} °C^{-1}. If the seal processing temperature is 450°C ,  what stress can be expected in the glass at 25 °C?

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It is assumed that all stresses are relieved at 450°C. Therefore, by Eqn (8.25)

\sigma=E(g)[\alpha(c)-\alpha(g)](T-T_{o})                (8.25)

the thermal stress produced in the glass at 25 °C is \sigma =0.7 \times 10^6/(1-0.27)[7.2 \times 10^{-6}-6.8 \times 10^{-6}](450-25)=163kg/cm^2. This value should be compared to the 5500 kg/cm^2 compressive (fracture) strength of the glass. The undesirable tensile stress that develops underscores the need for high-toughness solder glasses.