Question 7.C-L.4: Express the concentrations of each of the following solution...
Express the concentrations of each of the following solutions in terms of molarity:
a. 2.50 L of solution contains 1.25 mol of solute.
b. 225 mL of solution contains 0.486 mol of solute.
c. 100 mL of solution contains 2.60 g of NaCl solute.
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a. The data may be substituted directly into Equation 7.5:
M = \frac{moles of solute}{liters of solution} (7.5)
M = \frac{1.25 mol solute}{2.50 L solution} = 0.500 \frac{ mol solute}{ L solution}
The solution is 0.500 molar, or 0.500 M.
b. In this problem, the volume of solution must be converted to liters before the data are substituted into Equation 7.5:
(225 \cancel{mL} solution) (\frac{ 1 L}{1000 \cancel{mL}}) = 0.225 L solution
M = \frac{0.486 mol solute}{0.225 L solution} = 2.16 \frac{mol solute}{L solution}
The solution is 2.16 molar, or 2.16 M.
c. In this problem, the volume of solution must be converted to liters and the mass of solute must be converted to moles before the data can be substituted into Equation 7.5:
(100 \cancel{mL} solution) (\frac{ 1 L}{1000 \cancel{mL}}) = 0.100 L solution
(2.60 \cancel{g} \cancel{NaCl})(\frac{1 mol NaCl}{58.44 \cancel{g} \cancel{NaCl}}) = 0.0445 mol NaCl
In the last calculation, the factor \frac{1 mol NaCl}{58.44 f NaCl} comes from the calculated formula weight of 58.44 u for NaCl. The data are now substituted into Equation 7.5:
M = \frac{0.0445 mol NaCl}{0.100 L solution} = 0.445 \frac{mol NaCl}{L solution}
The solution is 0.445 molar, or 0.445 M.