Question 10.5: Parallel plane nongray walls are D = 2.5 cm apart and are at...

Parallel plane nongray walls are D = 2.5 cm apart and are at uniform temperatures T_1 = 1100 K and T_2 = 550 K . Pure CO_2 gas at 10-atm pressure and T_g = 550 K is between the walls. The hemispherical spectral emissivity for both walls is approximated as a function of wave number by the following table:

\eta (cm^{-1}) \epsilon _\eta \eta (cm^{-1}) \epsilon _\eta
0 to 500 0.37 1150 to 2200 0.45
500 to 750 0.26 2200 to 2500 0.65
750 to 850 0.32 2500 to 3600 0.61
850 to 1000 0.37 3600 to 3750 0.69
1000 to 1150 0.46 3750 to ∞ 0.73

Assume that only the 15-, 10.4-, 9.4-, 4.3-, and 2.7-μm CO_2 bands participate in the radiative transfer. Compute the total heat flux being added to wall 2.

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In Example 10.3 the spectral exchange was found for radiation between infinite parallel plates with a gas between them. The total energy added to plate 2 is found by integrating Equation 10.77b over all wave numbers:

q_{\lambda ,2}=\frac{1}{1-(1-\epsilon _{\lambda ,1})(1-\epsilon _{\lambda ,2})\overline{t_\lambda ^2} } \left\{\epsilon _{\lambda ,1}\epsilon _{\lambda ,2}\overline{t}_\lambda(E_{\lambda b,2}-E_{{\lambda b,1}})+\epsilon _{\lambda ,2}(1-\overline{t}_\lambda )\times [1+(1-\epsilon _{\lambda ,1})\overline{t}_\lambda](E_{\lambda b,2}-E_{{\lambda b,g}})\right\}             (10.77b)

q_{2}=\int_{\eta =0}^{\infty }{\frac{\epsilon _{\eta ,1}\epsilon _{\eta ,2}\overline{t}_\eta (E_{\eta b,2}-E_{\eta b,1})+\epsilon _{\eta ,2}(1-\overline{t}_\eta )[1+(1-\epsilon _{\eta ,1})\overline{t}_\eta ](E_{\eta b,g}) }{1-(1-\epsilon _{\eta ,1})(1-\epsilon _{\eta ,2})\overline{t^2_\eta } } }d\eta

In this example \epsilon_{η,1} = \epsilon_{η,2} and T_g = T_2, so q_2 simplifies to

q_{2}=-\int_{0}^{\infty }{\frac{\epsilon _{\eta ,1}\overline{t}_\eta (E_{\eta b,1}-E_{\eta b,2}) }{1-(1-\epsilon _{\eta ,1})^2\overline{t^2_\eta } } }d\eta

The integration is expressed as a sum over wave number bands. For the lth band let \epsilon _{\eta ,1}= \epsilon _{I} and \overline{t}_\eta =\overline{t} _l

q_2=-\sum\limits_{I}{\frac{\epsilon _I^2\overline{t}_I[E_b(T_1)-E_b(T_2)]_I\Delta \eta _I }{1-(1-\epsilon _I)^2\overline{t^2_I} } }

where (E_b)_I Δη_I is the blackbody radiation in the Ith band. From Equation 10.31, \overline{t} is written as

U_v(v,r)=\frac{1}{c}\int_{\Omega =0}^{4\pi }{I_v}(r,S)d\Omega =\frac{4\pi }{c}\left[\frac{1}{4\pi } \int_{\Omega =0}^{4\pi }{I_v}(r,S)d\Omega \right] =\frac{4\pi }{c}\overline{I}_v(r)                 (10.31)

\overline{t}_I=1-\overline{\alpha }_I=1-\frac{\overline{A}_I }{\Delta \eta _I}

where \overline{A}_I is the integrated effective bandwidth that includes the integrated path-length variation for a parallel-plate geometry. The q_2 now becomes

q_2=-\sum\limits_{I}{\frac{\epsilon _I^2(1-\overline{A}_I/\Delta \eta _I )[E_b(T_1)-E_b(T_2)]_I\Delta \eta _I }{1-(1-\epsilon _I)^2(1-\overline{A}_I/\Delta \eta _I )^2} }

Some of the calculated quantities and the flux results are in the tables that follow. Values of \overline{A}_I for the bands were computed from the exponential wide-band correlations using the basic quantities in Table 9.2. The mean beam length from Table 10.2, L_e = 1.8D = 1.8 × 0.025 = 0.045 m, was used as the effective path length for the radiant intensities in the layer. The gas density is ρ = 9749 g/m^3 which gives a mass path length of ρL_e = 438.7 g/m^2 .
The procedure in Example 9.1 was followed for calculating values for each band. The band wave number spans Δη_l were computed from Table 10.3 with the \bar{A}_I obtained using the values from Table 9.2. Since the calculation for \bar{A}_I depends on the band limits, an iteration may be required to obtain the correct band limits. The band energies [E_b (T_1 ) -E_b (T_2 )]_I  Δη_I were

TABLE 10.2
Mean Beam Lengths for Radiation from Entire Medium Volume
Geometry of Radiating System Characterizing
Dimension
Mean Beam Length
for Optical
Thickness κλLe → 0,
Le,
Mean Beam
Length
Corrected for
Finite Optical
Thickness,a Le
C = Le/Le,0
Hemisphere radiating to element at center of base Radius R R R 1
Sphere radiating to its surface Diameter D 2 0.65D 0.97
Circular cylinder of infinite height
radiating to concave bounding
surface
Circular cylinder of semi-infinite
height radiating to:
Diameter D 3 D 0.95D 0.95
Element at center of base Diameter D 0.77D 0.90D 0.9
Entire base
Circular cylinder of height equal
to diameter radiating to:
Diameter D 2qqq 0.65D 0.8
Element at center of base Diameter D 0.71D 0.92
Entire surface
Circular cylinder of height equal
to two diameters radiating to:
Diameter D 0.77D 0.60D 0.9
Plane end Diameter D 0.73D 0.60D 0.82
Concave surface Diameter D 0.82D 0.76D 0.93
Entire surface
Circular cylinder of height equal
to one-half the diameter radiating to:
Diameter D 0.80D 0.73D 0.91
Plane end Diameter D 0.48D 0.43D 0.9
Concave surface Diameter D 0.52D 0.46D 0.88
Entire surface Diameter D 0.50D 0.45D 0.9
Cylinder of infinite height and
semicircular cross section radiating
to element at center of plane
rectangular face
Infinite slab of medium radiating to:
Radius R 1.26R 0.9
Element on one face Slab thickness D 2D 1.8D 0.9
Both bounding planes Slab thickness D 2D 1.8D 0.9
Cube radiating to a face
Rectangular parallelepipeds 1 × 1 × 4
radiating to:
Edge X qqqqq 0.6X 0.9
1 × 4 face Shortest edge X 0.90X 0.82X 0.91
1 × 1 face Shortest edge X 0.86X 0.71X 0.83
All faces 1 × 2 × 6 radiating to: Shortest edge X 0.89X 0.81X 0.91
2 × 6 face Shortest edge X 1.18X
1 × 6 face Shortest edge X 1.24X
1 × 2 face Shortest edge X 1.18X
All faces Shortest edge X 1.20X
Medium between infinitely long
parallel concentric cylinders
Radius of outer
cylinder R and
of inner
cylinder r
2(R–r) See Anderson and
Handvig (1989)
Medium volume in the space between
the outside of the tubes in an infinite
tube bundle and radiating to a single
tube:
Equilateral triangular array: Tube diameter
S = 2D D, and spacing 3.4(S–D) 3.0(S–D) 0.88
S = 3D between tube 4.45(S–D) 3.8(S–D)
Square array: centers, S
S = 2D 4.1(S–D) 3.5(S–D) 0.85
a Corrections are those suggested by Hottel (1954), Hottel and Sarofim (1967) or Eckert and Drake (1959). Corrections
were chosen to provide maximum Le where these references disagree.
TABLE 10.3
Approximate Band Limits for Parallel-Plate Geometry
Band limits  η (cm^{−1}) ª
Gas Band λ (μm) Band center  η (cm^{−1}) Lower Upper
CO_2 15 667 667- (\overline{A}_{15} /  1 .78) 667 + (\overline{A}_{15} /  1 .78)
10.4 960 849 1013
9.4 1060 1013 1141
4.3 2350 2350 – (\overline{A}_{4.3} /  1 .78) 2430
2.7 3715 3715 –(\overline{A}_{2.7} /  1 .76) 3750
H_2O 6.3 1600 1600 –(\overline{A}_{6.3} /  1 .6) 1600 +(\overline{A}_{6.3} /  1 .6)
2.7 3750 3750 –(\overline{A}_{2.7} /  1 .4) 3750 + (\overline{A}_{2.7} /  1 .4)
1.87 5350 4620 6200
1.38 7250 6200 8100
ª \overline{A} are found for various bands as in Example 9.1. Terms such as \overline{A}_{15} /1.78 are \overline{A} /2(1− τ_g ) from Table 1 and 2 and Equation 17 of Edwards and Nelson (1962). Source: Edwards, D. K., and Nelson, K. E.: Rapid Calculation of Radiant Energy Transfer between Nongray Walls and Isothermal H_2O or CO_2 Gas, JHT, vol. 84, no. 4, pp. 273–278, 1962; Edwards, D. K.: Radiant Interchange in a Nongray Enclosure Containing an Isothermal Carbon Dioxide–Nitrogen Gas Mixture, JHT, vol. 84, no. 1, pp. 1–11, 1962; Edwards, D. K., Glassen, L. K., Hauser, W. C., and Tuchscher, J. S.: Radiation Heat Transfer in Nonisothermal Nongray Gases, JHT, vol. 89, no. 3, pp. 219–229, 1967.

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