Question 9.3: SELLMEIER EQUATION AND DIAMOND The relevant Sellmeier coeffi...
SELLMEIER EQUATION AND DIAMOND The relevant Sellmeier coefficients for diamond are given in Table 9.2. Calculate its refractive index at 550 nm (green light) to three decimal places.
Table 9.2 Sellmeier and Cauchy coefficients | ||||||
Sellmeier | ||||||
A_{1} | A_{2} | A_{3} | \lambda _{1} (\mu m) | \lambda _{2} (\mu m) | \lambda _{3} (\mu m) | |
SiO_{2} (fused silica) | 0.6967490 | 0.4082180 | 0.8908150 | 0.0690660 | 0.1156620 | 9.9005590 |
86.5% SiO_{2}–13.5% GeO_{2} |
0.711040 | 0.451885 | 0.704048 | 0.0642700 | 0.129408 | 9.425478 |
GeO_{2} | 0.80686642 | 0.71815848 | 0.85416831 | 0.068972606 | 0.15396605 | 11.841931 |
Sapphire | 1.023798 | 1.058264 | 5.280792 | 0.0614482 | 0.110700 | 17.92656 |
Diamond | 0.3306 | 4.3356 | 0.1750 | 0.1060 | ||
Cauch | ||||||
Range of hf (eV) | n_{−2} (eV^{2} ) | n_{0} | n_{2} (eV^{−2}) | n_{4} (eV^{−4}) | ||
Diamond | 0.05–5.47 | −1.07 × 10^{−5} | 2.378 | 8.01 × 10^{−3} | 1.04 × 10^{−4} | |
Silicon | 0.002–1.08 | −2.04 × 10^{−8} | 3.4189 | 8.15 × 10^{−2} | 1.25 × 10^{−2} | |
Germanium | 0.002–0.75 | −1.0 × 10^{−8} | 4.003 | 2.2 × 10^{−1} | 1.4 × 10^{−1} |
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The Sellmeier dispersion relation for diamond is
n^{2}=1+\frac{0.3306 \lambda^{2}}{\lambda^{2}-(175 nm )^{2}}+\frac{4.3356 \lambda^{2}}{ \lambda^{2}-(106 nm )^{2}}
=1+\frac{0.3306(550 nm )^{2}}{(550 nm )^{2}-(175 nm )^{2}}+\frac{4.3356(550 nm )^{2}}{(550 nm )^{2}-(106 nm )^{2}}=5.8707
So that n = 2.423
which is about 0.1 percent different than the experimental value of 2.426.
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