Question 4.P.2: Nitrogen at 12 MN/m² pressure is fed through a 25 mm diamete...

Nitrogen at 12 MN/m² pressure is fed through a 25 mm diameter mild steel pipe to a synthetic ammonia plant at the rate of 1.25 kg/s. What will be the pressure drop over a 30 m length of pipe for isothermal flow of the gas at 298 K? Absolute roughness of the pipe surface = 0.005 mm. Kilogram molecular volume = 22.4 m³. Viscosity of nitrogen = 0.02 mN s/m².

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Molecular weight of nitrogen = 28 kg/kmol.
Assuming a mean pressure in the pipe of 10 MN/m², the specific volume, v_m at 10 MN/m² and 298 K is:

v_m=(22.4 / 28)\left(101.3 / 10 \times 10^3\right)(298 / 273)=0.00885  m ^3 / kmol

Reynolds number, \rho u d / \mu=d(G / A) / \mu).

A=(\pi / 4)(0.025)^2=4.91 \times 10^{-3}  m ^2.

(G / A)=\left(1.25 / 4.91 \times 10^{-3}\right)=2540  kg / m ^2 s

and:                       R e=\left(0.025 \times 2540 / 0.02 \times 10^{-3}\right)=3.18 \times 10^6

From Fig. 3.7, for R e=3.18 \times 10^6 and e / d=(0.005 / 25)=0.0002,

R / \rho u^2=0.0017

In equation 4.57 and neglecting the first term:

\left(P_2-P_1\right) / v_m+4\left(R / \rho u^2\right)(l / d)(G / A)^2=0

or:      P_1-P_2=4 v_m\left(R / \rho u^2\right)(l / d)(G / A)^2

=4 \times 0.00885(0.0017)(30 / 0.025)(2540)^2

= 466,000 N/m² or 0.466 MN/m²

This is small in comparison with P_1=12  MN / m ^2, and the average pressure of 10 MN/m² is seen to be too low. A mean pressure of 11.75 kN/m² is therefore selected and the calculation repeated to give a pressure drop of 0.39 MN/m². The mean pressure is then (12+11.61) / 2=11.8 MN / m ^2 which is close enough to the assumed value.
It remains to check if the assumption that the kinetic energy term is negligible is justified.

Kinetic energy term =(G / A)^2 \ln \left(P_1 / P_2\right)=(2540)^2 \ln (12 / 11.61)=2.13 \times 10^5 kg 2 / m 4 s 2

The term \left(P_1-P_2\right) / v_m, where v_m is the specific volume at the mean pressure of 11.75  MN / m ^2=\left(0.39 \times 10^6\right) / 0.00753=5.18 \times 10^7  kg ^2 / m ^4 s.
Hence the omission of the kinetic energy term is justified

and the pressure drop =\underline{\underline{0.39  MN / m ^2}}

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