Question E.1: From data in the steam tables, find: a. The specific volume ...
From data in the steam tables, find:
a. The specific volume of superheated steam at 816 kPa and 512°C.
b. The temperature and specific entropy of superheated steam at P = 2950 kPa and H = 3150.6 kJ·kg^{−1}.
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(a) The following table shows specific volumes from Table E.2 for superheated steam at conditions adjacent to those specified:
P/kPa | t = 500°C | t = 512°C | t = 550°C |
800 | 443.17 | 472.49 | |
816 | V = ? | ||
825 | 429.65 | 458.10 |
Substitution of values in Eq. (E.2) with M = V, X = t, and Y = P yields:
M=\left[\left(\frac{X_2-X}{X_2-X_1}\right) M_{1,1}+\left(\frac{X-X_1}{X_2-X_1}\right) M_{1,2}\right] \frac{Y_2-Y}{Y_2-Y_1}
+\left[\left(\frac{X_2-X}{X_2-X_1}\right) M_{2,1}+\left(\frac{X-X_1}{X_2-X_1}\right) M_{2,2}\right] \frac{Y-Y_1}{Y_2-Y_1} (E.2)
V=\left[\frac{38}{50}(443.17)+\frac{12}{50}(472.49)\right] \frac{9}{25}+\left[\frac{38}{50}(429.65)+\frac{12}{50}(458.10)\right] \frac{16}{25}=441.42 \mathrm{~cm}^3 \cdot \mathrm{g}^{-1}
(b) The following table shows enthalpy data from Table E.2 for superheated steam at conditions adjacent to those specified:
P/kPa | t_1=350^{\circ} \mathrm{C} | t = ? | t_2=375^{\circ} \mathrm{C} |
2900 | 3177.4 | ||
2950 | H_{t_1} | H = 3150.6 | H_{t_2} |
3000 | 3117.5 | 3175.6 |
Here, the direct use of Eq. (E.2) is not convenient. Rather, for P = 2950 kPa, interpolate linearly at t1 = 350°C for H t 1 and at t2 = 375°C for H t 2 , applying Eq. (E.1) twice, first at t1 and second at t2, with M = H and X = P:
H_{t_1}=\frac{50}{100}(3119.7)+\frac{50}{100}(3117.5)=3118.6 (E.1)
H_{t_2}=\frac{50}{100}(3177.4)+\frac{50}{100}(3175.6)=3176.5
A third linear interpolation between these values with M = t and X = H in Eq. (E.1) yields:
t=\frac{3176.5-3150.6}{3176.5-3118.6}(350)+\frac{3150.6-3118.6}{3176.5-3118.6}(375)=363.82^{\circ} \mathrm{C}
Given this temperature, a table of entropy values can now be constructed:
P/kPa | t = 350°C | t = 363.82°C | t = 375°C |
2900 | 6.7654 | 6.8563 | |
2950 | S = ? | ||
3000 | 6.7471 | 6.8385 |
Application of Eq. (E.2) with M = S, X = t, and Y = P yields:
S=\left[\frac{11.18}{25}(6.7654)+\frac{13.82}{25}(6.8563)\right] \frac{50}{100}
+\left[\frac{11.18}{25}(6.7471)+\frac{13.82}{25}(6.8385)\right] \frac{50}{100}=6.8066 \mathrm{~kJ} \cdot \mathrm{mol}^{-1}
As a check, one can apply Eq. (E.2) with M = H, X = t, and Y = P, confirming that doing so produces H = 3150.6 kJ·kg^{−1}.