Question 8.3: Given the Lewis symbols for nitrogen and fluorine in Figure ...

Given the Lewis symbols for nitrogen and fluorine in Figure 8.2, predict the formula of the stable binary compound (a compound composed of two elements) formed when nitrogen reacts with fluorine and draw its Lewis structure.

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Analyze   The Lewis symbols for nitrogen and fluorine reveal that nitrogen has five valence electrons and fluorine has seven.
Plan   We need to find a combination of the two elements that results in an octet of electrons around each atom. Nitrogen requires three additional electrons to complete its octet, and fluorine requires one. Sharing a pair of electrons between one N atom and one F atom will result in an octet of electrons for fluorine but not for nitrogen. We therefore need to figure out a way to get two more electrons for the N atom.
Solve   Nitrogen must share a pair of electrons with three fluorine atoms to complete its octet. Thus, the binary compound these two elements form must be NF_{3}:

\overset{..}{\underset{\cdot }{\cdot N\cdot}} + 3   \overset{..}{\underset{\cdot \cdot }{\cdot F:}}\longrightarrow \begin{matrix} \overset{..}{\underset{\cdot \cdot }{:F:}} \overset{\cdot \cdot }{\underset{\overset{\cdot \cdot}{\underset{\cdot \cdot }{:F: } } }{N}} \overset{\cdot \cdot }{\underset{\cdot \cdot }{:F:}} \end{matrix}\longrightarrow \begin{matrix} \overset{\cdot \cdot }{\underset{\cdot \cdot }{:F}} \overset{\cdot \cdot }{\underset{\overset{}{\underset{\cdot \cdot }{:F: } } }{\underset{|}{-N-} }} \overset{\cdot \cdot }{\underset{\cdot \cdot }{F:}} \end{matrix}

Check   The Lewis structure in the center shows that each atom is surrounded by an octet of electrons. Once you are accustomed to thinking of each line in a Lewis structure as representing two electrons, you can just as easily use the structure on the right to check for octets.

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