Question 7.15: On a space shuttle, LiOH is used to absorb exhaled CO2 from ...

On a space shuttle, LiOH is used to absorb exhaled CO_{2} from breathing air to form LiHCO_{3}.

LiOH(s) + CO_{2}(g) → LiHCO_{3}(s)

What is the percent yield of LiHCO_{3} for the reaction if 50.0 g of LiOH gives 72.8 g of LiHCO_{3}?

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STEP 1   State the given and needed quantities (moles).

ANALYZE THE PROBLEM Given Need Connect
50.0 g of LiOH (reactant), 72.8 g of LiHCO_{3} (actual product) percent yield of LiHCO_{3} molar masses, mole-mole factor , percent yield expression
Equation
LiOH(s) + CO_{2}(g) → LiHCO_{3}(s)

STEP 2   Write a plan to calculate the theoretical yield and the percent yield.
Calculation of theoretical yield:

grams  of  LiOH      \boxed{\begin{array}{l}\text{Molar}\\\text{Mass}\end{array}} →      moles  of  LiOH     \boxed{\begin{array}{l}\text{Mole-mole}\\\text{factor}\end{array}} →    moles  of  LiHCO_{3}      \boxed{\begin{array}{l}\text{Molar}\\\text{Mass}\end{array}} →      \underset{Theoretical  yield}{grams  of  LiHCO_{3}}

Calculation of percent yield:

Percent yield(%)= \frac{acntal  yield  of  LiHCO_{3}}{theoretical  yield  of  LiHCO_{3}} \times 100%

STEP 3 Use coefficients to write mole-mole factors; write molar mass factors.

\begin{array}{r c}\boxed{\begin{matrix} 1  mole  of  LiOH = 23.95  g  of  LiOH \\\frac{23.95  g  LiOH}{1  mole  LiOH} \text{ and } \frac{1  mole  LiOH}{23.95  g  LiOH} \end{matrix}} & \boxed{\begin{matrix} 1  mole  of  LiHCO_{3} = 67.96  g  of  LiHCO_{3} \\ \frac{67.96  g  LiHCO_{3}}{ 1  mole  LiHCO_{3}}\text{ and }\frac{1  mole  LiHCO_{3}}{67.96  g  LiHCO_{3}} \end{matrix}}\end{array}

 

\begin{array}{r c}\boxed{\begin{matrix} 1  mole  of  LiHCO_{3}= 1  mole  of  LiOH \\\frac{1  mole  LiHCO_{3}}{1  mole  LiOH} \text{ and } \frac{1  mole  LiOH}{1  mole  of  LiHCO_{3}} \end{matrix}}\end{array}

STEP 4  Calculate the percent yield by dividing the actual yield (given) by the theoretical yield and multiplying the result by 100%.
Calculation of theoretical yield:

\underset{Three  SFs }{50.0   \cancel{g  LiOH}}     \times    \overset{Exact}{\underset{Four  SFs }{\boxed{\frac{1  \cancel{mole  LiOH}}{23.95  \cancel{ g  LiOH}} }}}   \times    \overset{Exact}{\underset{Exact }{\boxed{\frac{1  \cancel{mole  LiHCO_{3}}}{1  \cancel{ mole  LiOH}} }}}   \times    \overset{Four  SFs}{\underset{Exact }{\boxed{\frac{67.96  g  LiHCO_{3}}{1  \cancel{ mole  LiHCO_{3}}} }}} = \underset{Three  Sfs }{142  g  of  LiHCO_{3}}

Calculation of percent yield:

\frac{acntal  yield  (given) }{theoretical  yield  (calculated)} \times 100 % = \overset{Three  Sfs}{\underset{Three  Sfs}{\frac{72.8  \cancel{g  LiHCO_{3}}}{142  \cancel{g  LiHCO_{3}}}}} \times 100 % =\underset{Three  Sfs }{51.3}%

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