Question 4.11: WRITING HALF-REACTIONS Write unbalanced half-reactions for t...

WRITING HALF-REACTIONS

Write unbalanced half-reactions for the following net ionic equations:

(a) Mn^{2+}(aq)  +  ClO_{3}^{-}(aq)  →  MnO_{2}(s)  +  ClO_{2}(aq)

(b) Cr_{2}O_{7}^{2-}(aq)  +  Fe^{2+}(aq)  →  Cr^{3+}(aq)  +  Fe^{3+}(aq)

STRATEGY
Look at each equation to see which atoms are being oxidized (increasing in oxidation number) and which are being reduced (decreasing in oxidation number).

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(a) Oxidation:   Mn^{+2}(aq)  →  MnO_{2}(s)     Mn goes from +2 to +4

Reduction:     ClO_{3}^{-}(aq)  →  ClO_{2}(aq)     Cl goes from +5 to +4

(b) Oxidation:    Fe^{2+}(aq)  →  Fe^{3+}(aq)      Fe goes from +2 to +3

Reduction:     Cr_{2}O_{7}^{2-}(aq)  →  Cr^{3+}(aq)     Cr goes from +6 to +3

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