Question 11.4: Does the equilibrium mixture of the following reaction conta...

Does the equilibrium mixture of the following reaction contain mostly reactants or products?

HF(aq) + H_{2}O(l) \xrightleftharpoons[]{} H_{3}O^{+}(aq) + F^{-}(aq)
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From Table 11.3, we see that HF is a weaker acid than H_{3}O^{+} and that H_{2}O is a weaker base than F^{-}. Thus, the equilibrium mixture contains mostly reactants.

\underset{\underset{acid }{Weaker} }{ HF(aq)} + \underset{\underset{base }{Weaker} }{ H_{2}O(l)} \xrightleftharpoons[]{} \underset{\underset{acid }{Stronger} }{ H_{3}O^{+}(aq)} + \underset{\underset{base }{Stronger} }{F^{-}(aq) }
TABLE 11 .3 Relative Strengths of Acids and Bases
 \quad\quad

Acid Conjugate Base  

\quad\quad

Strong Acids Weak Bases
Hydroiodic acid HI I^{-} Iodide ion
Hydrobromic acid HBr Br^{-} Bromide ion
Perchloric acid HClO_{4} ClO{4}^{-} Perchlorate ion
Hydrochloric acid HCl Cl^{-} Chloride ion
Sulfuric acid H_{2}SO_{4} HSO_{4}^{-} Hydrogen sulfate ion
Nitric acid HNO_{3} NO_{3}^{-} Nitrate ion
Hydronium ion H_{3}O^{+} H_{2}O Water
Weak Acids Strong Bases
Hydrogen sulfate ion HSO_{4}^{-} SO_{4}^{2-} Sulfate ion
Phosphoric acid H_{3}PO_{4} H_{2}PO_{4}^{-} Dihydrogen phosphate ion
Nitrous acid HNO_{3} NO_{2}^{-} Nitrite ion
Hydrofluoric acid HF F^{-} Fluoride ion
Acetic acid HC_{2}H_{3}O_{2} C_{2}H_{3}O_{2}^{-} Acetate ion
Carbonic acid H_{2}CO_{3} HCO_{3}^{-} Bicarbonate ion
Hydrosulfuric acid H_{2}S HS^{-} Hydrogen sulfide ion
Dihydrogen phosphate ion H_{2}PO_{4}^{-} HPO_{4}^{2-} Hydrogen phosphate ion
Ammonium ion NH_{4}^{+} NH_{3} Ammonia
Hydrocyanic acid HCN CN^{-} Cyanide ion
Bicarbonate ion HCO_{3}^{-} CO_{3}^{-} Carbonate ion
Methylantmonium ion CH_{3}  NH_{3}^{+} CH_{3}  NH_{2} Methylamine
Hydrogen phosphate ion HPO_{4}^{2-} PO_{4}^{3-} Phosphate ion
Water H_{2}O OH^{-} Hydroxide ion

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