Question 27.6: In the crystallizer of Example 27.5, a growth rate G of 0.00......

In the crystallizer of Example 27.5, a growth rate G of 0.0018 ft/h (0.00055 m/h) is anticipated, and a predominant crystal size of 20 mesh is desired. How large must the magma volume in the crystallizer be; what nucleation rate B° is necessary; and what is the screen analysis of the product, assuming that the operation conforms to all the requirements of the mixed suspension-mixed product crystallization?

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The screen opening of a 20-mesh standard screen is, from Appendix 20, 0.0328 in., or 0.00273 ft. This dimension can be used for L, and the shape factor a [Eq. (27.16)] is assumed to be unity. From Example 27.5, the volume flow rate of mother liquor in the product magma is

v_p=a L^3    (27.16)

Q=\frac{44,520}{82.5}=540~ ft ^3 / h

Since, when z = 3, L_{pr} = 0.00273, Eq. (27.28) gives for the drawdown time and the volume of liquid in the crystallizer

z \equiv \frac{L}{G \tau}   (27.28)

\tau=\frac{L_{p r}}{3 G}=\frac{0.00273}{3 \times 0.0018}=0.506~ h \quad V_{ c }=0.506 \times 540=273 ~ft ^3

The total magma volume is 273/0.85 = 321 ft³, or 2400 gal.
The nucleation rate is, from Eq. (27.44), since C = 10,000 lb/h,

B^{\circ}=\frac{C n_c}{m_c V_c}=\frac{C}{6 a \rho_c(G \tau)^3 V_c}=\frac{9 C}{2 a \rho_c V_c L_{p r}^3}    (27.44)

\begin{aligned}B^{\circ}& =\frac{9 \times 10,000}{2 \times 105 \times 273 \times 0.00273^3} \\ & =7.72 \times 10^9 \text { nuclei } / t ^3- h \left(2.74 \times 10^9 \text { nuclei } / m ^3- h \right)\end{aligned}

By Eq. (27.40), the zero-size particle density is n° = 7.72 × 10^{7}/0.0018 = 4.289 × 10^{10} nuclei/ft^4 The value of L/Gτ is L/(0.0018)(0.506) = 1.1 × 10³ L. The equation for the number-density distribution is, from Eq. (27.27),

B^{\circ}=G n^{\circ}    (27.40)

\begin{aligned}& \int_{n^{\circ}}^n \frac{d n}{n}=-\frac{1}{G \tau} \int_0^L d L \\ & \ln \frac{n^{\circ}}{n}=\frac{L}{G \tau}\end{aligned}    (27.27)

\log n=\log n^{\circ}-\frac{1.1 \times 10^3 L}{2.3026}=10.632-4.777 \times 10^2 L

This equation is plotted in Fig. 27.16.

The screen analysis is found by reading ordinates from Fig. 27.15c for values of z corresponding to mesh openings. For example, for the 20-mesh point, where z = 3, x_m is 0.35. In general,

z=\frac{L}{\tau G}=\frac{L}{0.506 \times 0.0018}=1098 L

Details are given in Table 27.2.

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TABLE 27.2
Mesh Size z Screen analysis, %
ft mm Cumulative Differential
8 0.0078 2.37 8.5 97 3
9 0.0065 1.98 7.1 93 4
10 0.0054 1.65 5.9 84 9
12 0.0046 1.40 5 74 10
14 0.0038 1.16 4.2 61 13
16 0.0033 1.01 3.6 48 13
20 0.0027 0.82 3.0 35 13
24 0.0023 0.70 2.5 25 10
28 0.0019 0.58 2.1 17 8
32 0.0016 0.49 1.8 11 6
35 0.0014 0.43 1.5 6 5
42 0.0011 0.34 1.2 4 2

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