Question 13.4.5: Calculate the boiling point of a solution. What is the boili......

Calculate the boiling point of a solution.

What is the boiling point of a solution containing 40.0 g I_{2} and 250 g benzene (C_{6}H_{6})?

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You are asked to calculate the boiling point of a solution.
You are given the mass of solute and solvent in the solution.
The boiling point of the solution is the normal boiling point plus the boiling point elevation. Using data from Table 13.4.1,
T_{bp} = 80.1 °C + (2.53 °C/m)(m_{solute})i
The concentration of I_{2}, a nonelectrolyte, is

m_{I_{2}} = \frac{\text{mol I}_{2}}{\text{kg benzene}} = \frac{\left(40.0\text{ g}\right)\left(\frac{1{\text{ mol I}_{2}}}{253.8\text{ g}} \right) }{0.250 \text{ kg benzene}} = 0.630 m

Use equation 13.9 to calculate the boiling point of the solution

T_{bp} = 80.1 °C + (2.53 °C/m)(0.630 m)(1) = 81.7 °C

ΔT_{bp} = K_{bp}m_{solute}i         (13.9)

Is your answer reasonable? A solute was added to the solvent, so the boiling point of the solution is greater than the boiling point of the pure solvent.

Table 13.4.1   Boiling Points and Elevation
Constants for Common Solvents

Solvent \pmb{T_{bp}} (°C) \pmb{K_{bp}} (°C/m)
Water 100 0.512
Benzene 80.1 2.53
Acetic acid 118.1 3.07
Nitrobenzene 210.9 5.24
Phenol 182 3.56
Camphor 207.4 5.61

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