Question 1.55: Calculate the percentage composition of the following compou......

Calculate the percentage composition of the following compounds:

(i) Urea CO(NH2)2CO(NH_2)_2

(ii) Copper sulphate CuSO4.5H2OCuSO_4.5H_2O.

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(i) Urea : CO(NH2)2CO(NH_2)_2

Molar mass of urea = 12 + 16 + 2 (14 + 2) = 60

Mass of carbon = 12

Mass percentage of carbon = 1260×100=20%\frac{12}{60} \times 100 = 20 \%

Mass of oxygen = 16

Mass percentage of oxygen = 1660×100=26.67%\frac{16}{60} \times 100 = 26.67 \%

Mass of nitrogen = 2 × 14 = 28

Mass percentage of nitrogen = 2860×100=46.66%\frac{28}{60} \times 100 = 46.66 \%

Mass of H = 4 × 1 = 4

Mass percentage of hydrogen = 460×100=6.67%\frac{4}{60} \times 100 = 6.67 \%

(ii) Copper sulphate, CuSO4.5H2OCuSO_4.5H_2O

Molar mass of CuSO4.5H2OCuSO_4.5H_2O = 63.5 + 32 + 4 × 16 + 5 × 18

= 249.5

Mass of Cu = 63.5

Mass percentage of Cu = 63.5249.5×100=25.45\frac{63.5}{249.5} \times 100 = 25.45

Mass of S = 32

Mass percentage of S = 32249.5×100=12.82%\frac{32}{249.5} \times 100 = 12.82 \%

Mass of O = 9 × 16 = 144

Mass percentage of O = 144249.5×100=57.77%\frac{144}{249.5} \times 100 = 57.77 \%

Mass of H = 10 × 1 = 10

Mass percentage of H = 10249.5×100=4.01%\frac{10}{249.5} \times 100 = 4.01 \%

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