Coenzymes

Describe the reactive part of each of the following coenzymes and the way each participates in metabolic pathways:

a. FAD                    b. NAD+^+

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a. The oxidized form of FAD undergoes reduction when two nitrogen atoms in the flavin part react with 2H+2 H ^{+} and 2 e2\ e^{-} to give FADH2FADH _2. The coenzyme FAD is utilized in oxidation reactions that produce carbon-carbon double bonds (C=C).

b. The oxidized form of NAD+NAD ^{+} undergoes reduction when a carbon atom in the nicotinamide part reacts with 2H+2 H ^{+} and 2 e2\ e^{-}, to give NADH and H+H ^{+}. The coenzyme NAD+NAD ^{+} is utilized in oxidation reactions that produce carbon-oxygen double bonds (C=O).

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