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Question 11A.CQ.7: How is pyrophosphoric acid related to orthophosphoric acid?...

How is pyrophosphoric acid related to orthophosphoric acid?

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Pyrophosphoric acid (H_4P_2O_7) is the anhydride of orthophosphoric acid (H_3PO_4) and is obtained by the removal of a molecule of water from two molecules of H_3PO_4 as shown below:

2 H _3 PO _4\quad \xrightarrow{527\ K }\quad H _4 P _2 O _7+ H _2 O

Orthophosphoric                   Pyrophosphoric

acid                                         acid

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