How is pyrophosphoric acid related to orthophosphoric acid?
Pyrophosphoric acid (H_4P_2O_7) is the anhydride of orthophosphoric acid (H_3PO_4) and is obtained by the removal of a molecule of water from two molecules of H_3PO_4 as shown below:
2 H _3 PO _4\quad \xrightarrow{527\ K }\quad H _4 P _2 O _7+ H _2 O
Orthophosphoric Pyrophosphoric
acid acid