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Question 10.3: Identifying Intermolecular Forces Identify the likely kinds ......

Identifying Intermolecular Forces

Identify the likely kinds of intermolecular forces in the following substances:

(a) HCl           (b) CH_3CH_3          (c) CH_3NH_2         (d) Kr

STRATEGY

Look at the structure of each substance, and decide what intermolecular forces are present. All molecules have dispersion forces; polar molecules have dipole–dipole forces; and molecules with O-H, N-H, or F-H bonds have hydrogen bonds.

Step-by-Step
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(a) HCl is a polar molecule but can’t form hydrogen bonds. It has dipole–dipole forces and dispersion forces.

(b) CH_3CH_3 is a nonpolar molecule and has only dispersion forces.

(c) CH_3NH_2 is a polar molecule that can form hydrogen bonds. In addition, it has dipole– dipole forces and dispersion forces.

(d) Kr is nonpolar and has only dispersion forces.

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