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Question 10.4: In an experimental wetted wall column, pure carbon dioxide i......

In an experimental wetted wall column, pure carbon dioxide is absorbed in water. The mass transfer rate is calculated using the penetration theory, application of which is limited by the fact that the concentration should not reach more than 1 per cent of the saturation value at a depth below the surface at which the velocity is 95 per cent of the surface velocity. What is the maximum length of column to which the theory can be applied if the flowrate of water is 3 cm³/s per cm of perimeter?

Viscosity of water = 10^{-3} N s/m². Diffusivity of carbon dioxide in water = 1.5 x 10^{-9} m²/s

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For the flow of a vertical film of fluid, the mean velocity of flow is governed by equation 3.87 in which sinΦ is put equal to unity for a vertical surface:

u=\frac{\rho g\sin\phi s^{2}}{3\mu}        (equation 3.87)

u_{m}={\frac{\rho g s^{2}}{3\mu}}

where s is the thickness of the film.
The flowrate per unit perimeter (ρgs³/3μ) = 3 x 10^{-4} m²/s

and: s=\left({\frac{3\times10^{-4}\times10^{-3}\times3}{1000\times9.81}}\right)^{1/3}

= 4.51 × 10^{-4} m

The velocity u_{x} at a distance y’ from the vertical column wall is given by equation 3.85 (using y’ in place of y) as:

u_{x}={\frac{\rho g\sin\theta}{\mu}}(s y-{\textstyle{\frac{1}{2}}}y^{2})              (3.85)

u_{x}={\frac{\rho g(s y^{\prime}-{\frac{1}{2}}y^{\prime2})}{\mu}}

The free surface velocity u_{s} is given by substituting s for y’ or:

u_{s}={\frac{\rho g s^{2}}{2\mu}}

Thus: {\frac{u_{x}}{u_{s}}}=2\left({\frac{y^{\prime}}{s}}\right)-\left({\frac{y^{\prime}}{s}}\right)^{2}=1-\left(1-{\frac{y^{\prime}}{s}}\right)^{2}

When u_{x}/u_{s} = 0.95, that is velocity is 95 per cent of surface velocity, then:

1\,-\,{\frac{y^{\prime}}{s}}=0.224

and the distance below the free surface is y = s – y’ = 1.010 x 10^{-4} m
The relationship between concentration C_{A}, time and depth is:

{\frac{C_{A}-C_{A o}}{C_{A i}-C_{A o}}}=\operatorname{erfc}\,\,\left({\frac{y}{2{\sqrt{D t}}}}\right)                  (equation 10.108)

The time at which concentration reaches 0.01 of saturation value at a depth of 1.010 x 10^{-4} m is given by:

0.01=\mathrm{erfc}\;\left(\frac{1.010\times10^{-4}}{2\sqrt{1.5\times10^{-9}t}}\right)

Thus: \operatorname{erf}\ \left({\frac{1.305}{\sqrt{t}}}\right)=0.99

Using Tables of error functions (Appendix A3, Table 12):

{\frac{1.305}{\sqrt{t}}}\,=\,1.822

and: t = 0.51s
The surface velocity is then u_{s}={\frac{\rho g s^{2}}{2\mu}}

= \frac{1000\times9.81\times(4.51\times10^{-4})^{2}}{2\times10^{-3}}

= 1 m/s

and the maximum length of column is: = (1 x 0.51) = \underline{\underline{0.51\ m}}

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