Question 2.14: Name the following acids: (a) HBrO(aq) (b) HCN(aq)...

Name the following acids:

(a) HBrO(aq)            (b) HCN(aq)

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STRATEGY

To name an acid, look at the formula and decide whether the compound is an oxoacid. If so, the name must reflect the number of oxygen atoms, according to Table 2.4. If the compound is not an oxoacid, it is named using the prefix hydro- and the suffix -ic acid.

(a) This compound is an oxoacid that yields hypobromite ion  (BrO^{-})  when dissolved in water. Its name is hypobromous acid.

(b) This compound is not an oxoacid but yields cyanide ion when dissolved in water. As a pure gas, HCN is named hydrogen cyanide. In water solution, it is called hydro-cyanic acid.

TABLE 2.4 Some Common Oxoacids and Their Anions

Oxoacid Oxoanion
HNO_{2} Nitrous acid NO^{-}_{2} Nitrite ion
HNO_{3} Nitric acid NO^{-}_{3} Nitrate ion
H_{3}PO_{4} Phosphoric acid PO^{3-}_{4} Phosphate ion
H_{2}SO_{3} Sulfurous acid SO^{2-}_{3} Sulfite ion
H_{2}SO_{4} Sulfuric acid SO^{2-}_{4} Sulfate ion
HClO Hypochlorous acid ClO^{-} Hypochlorite ion
HClO_{2} Chlorous acid ClO^{-}_{2} Chlorite ion
HClO_{3} Chloric acid ClO^{-}_{3} Chlorite ion
HClO_{4} Perchloric acid ClO^{-}_{4} Perchlorate ion

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