Question 23.2: The following condensed structures have the same formula, C8......

The following condensed structures have the same formula,  C_{8}H_{18}   Which of them represent the same molecule?

\pmb{(a)} \begin{matrix}  \quad\ \ CH_{3} \ \quad CH_{3} \\ | \quad\quad \quad | \\ \quad \quad \quad CH_{3}CHCH_{2}CHCH_{2}CH_{3} \end{matrix}\quad \pmb{(b)} \begin{matrix} \quad \quad CH_{3} \quad CH_{3} \\  \quad |\quad \quad \quad | \\ CH_3CH_{2}CHCH_{2}CHCH_{3}  \end{matrix} \quad \pmb{(c)} \begin{matrix} \quad\quad CH_{3} \quad \quad CH_{3} \\  \ \ \ |\quad \quad \quad \quad| \\  CH_{3}CHCH_{2}CH_{2}CHCH_{3}\end{matrix}

STRATEGY

Pay attention to the order of connection between atoms. Don’t get confused by the apparent differences caused by writing a structure right-to-left versus left-to-right.

Step-by-Step
The 'Blue Check Mark' means that this solution was answered by an expert.
Learn more on how do we answer questions.

Structure (a) has a straight chain of six carbons with  –CH_{3}  branches on the second and fourth carbons from the end. Structure (b) also has a straight chain of six carbons with  –CH_{3}  branches on the second and fourth carbons from the end and is therefore identi-cal to (a). The only difference between (a) and (b) is that one is written “forward” and one is written “backward.” Structure (c) has a straight chain of six carbons with  –CH_{3}   branches on the second and fifth carbons from the end, so it is an isomer of (a) and (b).

Related Answered Questions

Question: 23.8

Verified Answer:

The reaction of a carboxylic acid with an alcohol ...
Question: 23.WKC.1

Verified Answer:

The compound has 7 carbons and 16 hydrogens:  [lat...
Question: 23.7

Verified Answer:

(a) This ester is derived from propyl alcohol and ...
Question: 23.6

Verified Answer:

\\ \overset{1}{C}H_{3}\overset{2}{C}H_{2} \...
Question: 23.4

Verified Answer:

First, look at the parent name (hexane) and draw i...
Question: 23.3

Verified Answer:

The molecule has a chain of eight carbons (octane)...