Under load following conditions a reactor operates each day at full power for 12 hours, followed by a shutdown of 12 hours. Calculate the iodine concentration, I(t), over a 24 hour time span. Use periodic boundary conditions I(24 hr) = I(0).
Apply the integrating factor \mathrm{exp}(\lambda_{I}t) to Eq. (10.12):
\left[{\frac{d}{d t}}I(t)+\lambda_{I}I(t)\right]\exp(\lambda_{I}t)={\frac{d}{d t}}\{I(t)\exp(\lambda_{I}t)\}=\gamma_{I}\Sigma_{f}\phi\exp(\lambda_{I}t)
Integrate between 0 and t:
I(t)\exp(\lambda_{I}t)-I(0)=\int_0^{t}\gamma_{I}\Sigma_{f}\phi\exp(\lambda_{I}t^{\prime})d t^{\prime}={\frac{\gamma_{I}\Sigma_{f}\phi}{\lambda_{I}}}[\exp(\lambda_{I}t)-1]
Thus
I(t)=I(0)e^{-\lambda_{I}t}+\frac{\gamma_{I}\Sigma_{f}\phi}{\lambda_{I}}(1-e^{-\lambda_{I}t})\ \ \mathrm{for}\ 0\lt t\lt 12\mathrm{~hr}.
Let t^{\prime} = t – 12 \mathrm{hr}. Then while the reactor is shut down, no iodine is produced and thus
I(t)=I(12)e^{-\lambda_{I}t^{\prime}}\quad\qquad{\mathrm{for~}}12 \ \ \mathrm{h}\mathrm{r.\lt }t\lt 24\mathrm{~h}\mathrm{r.}
Now using the periodic boundary condition:
I(0)=I(24)=I(12)e^{-\lambda_{I}12}=\left\{I(0)e^{-\lambda_{I}12}+\frac{\gamma_{I}\Sigma_{f}\phi}{\lambda_{I}}(1-e^{-\lambda_{I}12})\right\}e^{-\lambda_{I}12}\ .
Solve for I(0):
I(0)=\frac{\gamma_{I}\Sigma_{f}\phi}{\lambda_{I}}\frac{(1-e^{-\lambda_{I}12})}{(1-e^{-\lambda_{I}24})}e^{-\lambda_{I}12}=\frac{\gamma_{I}\Sigma_{f}\phi}{\lambda_{I}}\frac{1}{(e^{\lambda_{I}12}+1)}
Thus
I(t)=\frac{\gamma_{I}\Sigma_{f}\phi}{\lambda_{I}}\frac{1}{\left(e^{\lambda_{I}12}+1\right)}e^{-\lambda_{I}t}+\frac{\gamma_{I}\Sigma_{f}\phi}{\lambda_{I}}(1-e^{-\lambda_{I}t})\ \ \mathrm{for}\ 0\lt t\lt 12\mathrm{~hr}.
I(t)=\frac{\gamma_{I}\Sigma_{f}\phi}{\lambda_{I}}\frac{e^{\lambda_{I}1{2}}}{\left(e^{\lambda_{I}12}+1\right)}e^{-\lambda_{I}t^{\prime}}\quad\mathrm{for}\,0\lt t^{\prime}\lt 12\,\mathrm{h}\mathrm{r}.,\,\,\,\,\mathrm{or}\,
I(t)=\frac{\gamma_{I}\Sigma_{f}\phi}{\lambda_{I}}\frac{e^{\lambda_{I}24}}{\left(e^{\lambda_{I}12}+1\right)}e^{-\lambda_{I}t}\quad\mathrm{for~}12\ \mathrm{hr.}\lt t\lt 24\mathrm{~hr}.