Using the VSEPR Model to Predict a Molecular Shape
Predict the shape of BrF_5.
STRATEGY
First, draw an electron-dot structure for BrF_5 to determine how many charge clouds surround the central bromine atom. Then use the VSEPR model to predict how the charge clouds are arranged.
\begin{matrix} \underset{\quad ╲ }{:\overset{..}{\underset{..}{F}}} \ \ \underset{|}{\overset{..}{:F:}} \ \ \ \underset{╱\quad }{\overset{..}{\underset{..}{\quad F:}}} \\ \underset{..}{Br} \ \\ \underset{\overset{..}{\underset{..}{:F}}}{\ \ \ \ \ \ ╱}\quad \underset{\overset{..}{\underset{..}{F:}}}{ ╲ \ \ \ } \ \ \ \ \ \end{matrix}The central bromine atom in BrF_5 has six charge clouds—five bonds and one lone pair— implying an octahedral arrangement. The five attached atoms and one lone pair give BrF_5 a square pyramidal shape: