Question 30.7: An exoergic reaction Now let’s use Equation 30.12 to calcula...

An exoergic reaction

Now let’s use Equation 30.12 to calculate the reaction energy when lithium is bombarded by a proton and two alpha particles are produced.

\mathrm{Q = (M_A+M_B-M_C-M_D)}c^2.                                (30.12)

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SET UP The reaction can be represented as

\mathrm{^1_1 H  +  ^7_3Li  \rightarrow {}^4_2He  +  ^4_2He.}

We need to use the definition of reaction energy, Equation 30.12. The masses we need are given in Table 30.2.

SOLVE From Table 30.2, we find the initial and final masses:

\mathrm{\begin{matrix} A: {}^1_1H & 1.007825  u & C:^4_2He& 4.002603  u \end{matrix} }

\mathrm{\begin{matrix} B: {^7_3Li} &\frac{7.016005  u}{8.023830  u} &     D: {}^4_2He &\frac{4.002603  u}{8.005206  u} \end{matrix} }

Four electron masses are included on each side. We see that

\mathrm{M_A  +  M_B  –  M_C  –  M_D = 0.018624  u.}

The mass decreases by 0.018624 u; from Equation 30.12, the reaction energy is

\mathrm{Q = (M_A+M_B-M_C-M_D)}c^2.                                (30.12)

Q = (0.018624 u)(931.5 MeV/u) = 17.35 MeV.

REFLECT The total mass decreases, so the total kinetic energy increases. The final total kinetic energy of the two separating α particles is 17.35 MeV greater than the initial total kinetic energy of the proton and the lithium nucleus.

Practice Problem: Find the Q value for the reaction \mathrm{^1_0n  +  ^{10}_5B  \rightarrow  ^7_3Li  +  ^4_2He.} Is this reaction exoergic or endoergic? Answers: 2.79 MeV, exoergic.

TABLE 30.2 Atomic masses of light elements
Element Atomic number,
Z
Mass number,
N
Atomic mass
u
 Mass number,
A
Hydrogen, H 1 0 1.007825 1
Deuterium, H 1 1 2.014101 2
Helium, He 2 1 3.016029 3
Helium, He 2 2 4.002603 4
Lithium, Li 3 3 6.015123 6
Lithium, Li 3 4 7.016003 7
Beryllium, Be 4 5 9.012183 9
Boron, B 5 5 10.012937 10
Boron, B 5 6 11.009305 11
Carbon, C 6 6 12.000000 12
Carbon, C 6 7 13.003355 13
Nitrogen, N 7 7 14.003074 14
Nitrogen, N 7 8 15.000109 15
Oxygen, O 8 8 15.994915 16
Oxygen, O 8 9 16.999132 17
Oxygen, O 8 10 17.999160 18
Source: Atomic Mass Evaluation 2013. M. Wang et al 2012 Chinese Phys. C 36 1603 doi:10.1088/1674-1137/36/12/003

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