Question 5.5: Calculate the volume occupied by 0.845 mol of nitrogen gas a...

Calculate the volume occupied by 0.845 mol of nitrogen gas at a pressure of 1.37 atm and a temperature of 315 K.

SORT The problem gives you the number of moles of nitrogen gas, the pressure, and the temperature. You want to find the volume. GIVEN n = 0.845 mol, P = 1.37 atm, T = 315 K
FIND V
STRATEGIZE You are given three of the four variables (P, T, and n) in the ideal gas law and asked to find the fourth (V). The conceptual plan shows how the ideal gas law provides the relationship between the given quantities and the quantity to be found. CONCEPTUAL PLAN
n, P, T     →      V
      PV = nRT
RELATIONSHIPS USED PV = nRT (ideal gas law)
SOLVE To solve the problem, first solve the ideal gas law for V.Then substitute the given quantities to calculate V.
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PV = nRT
V = \frac{nRT}{P}
V =\frac{0.845 \cancel{mol} \times 0.08206\frac{ L .\cancel{atm}}{ \cancel{mol} . \cancel{K}} \times 315\cancel{ K}}{ 1.37 \cancel{atm}}
= 15.9 L

CHECK The units of the answer are correct. The magnitude of the answer (15.9 L) makes sense because, as you will see in the next section, 1 mole of an ideal gas under standard temperature and pressure (273 K and 1 atm) occupies 22.4 L.
Although the temperature and pressure in this problem are not standard, they are close enough for a ballpark check of the answer. Since this gas sample contains 0.845 mol, a volume of 15.9 L is reasonable.

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