Question 11.4: Does the equilibrium mixture of the following reaction conta...
Does the equilibrium mixture of the following reaction contain mostly reactants or products?
HF(aq) + H_{2}O(l) \xrightleftharpoons[]{} H_{3}O^{+}(aq) + F^{-}(aq)The blue check mark means that this solution has been answered and checked by an expert. This guarantees that the final answer is accurate.
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From Table 11.3, we see that HF is a weaker acid than H_{3}O^{+} and that H_{2}O is a weaker base than F^{-}. Thus, the equilibrium mixture contains mostly reactants.
\underset{\underset{acid }{Weaker} }{ HF(aq)} + \underset{\underset{base }{Weaker} }{ H_{2}O(l)} \xrightleftharpoons[]{} \underset{\underset{acid }{Stronger} }{ H_{3}O^{+}(aq)} + \underset{\underset{base }{Stronger} }{F^{-}(aq) }TABLE 11 .3 Relative Strengths of Acids and Bases | |||||
\quad\quad
|
Acid | Conjugate Base |
\quad\quad |
||
Strong Acids | Weak Bases | ||||
Hydroiodic acid | HI | I^{-} | Iodide ion | ||
Hydrobromic acid | HBr | Br^{-} | Bromide ion | ||
Perchloric acid | HClO_{4} | ClO{4}^{-} | Perchlorate ion | ||
Hydrochloric acid | HCl | Cl^{-} | Chloride ion | ||
Sulfuric acid | H_{2}SO_{4} | HSO_{4}^{-} | Hydrogen sulfate ion | ||
Nitric acid | HNO_{3} | NO_{3}^{-} | Nitrate ion | ||
Hydronium ion | H_{3}O^{+} | H_{2}O | Water | ||
Weak Acids | Strong Bases | ||||
Hydrogen sulfate ion | HSO_{4}^{-} | SO_{4}^{2-} | Sulfate ion | ||
Phosphoric acid | H_{3}PO_{4} | H_{2}PO_{4}^{-} | Dihydrogen phosphate ion | ||
Nitrous acid | HNO_{3} | NO_{2}^{-} | Nitrite ion | ||
Hydrofluoric acid | HF | F^{-} | Fluoride ion | ||
Acetic acid | HC_{2}H_{3}O_{2} | C_{2}H_{3}O_{2}^{-} | Acetate ion | ||
Carbonic acid | H_{2}CO_{3} | HCO_{3}^{-} | Bicarbonate ion | ||
Hydrosulfuric acid | H_{2}S | HS^{-} | Hydrogen sulfide ion | ||
Dihydrogen phosphate ion | H_{2}PO_{4}^{-} | HPO_{4}^{2-} | Hydrogen phosphate ion | ||
Ammonium ion | NH_{4}^{+} | NH_{3} | Ammonia | ||
Hydrocyanic acid | HCN | CN^{-} | Cyanide ion | ||
Bicarbonate ion | HCO_{3}^{-} | CO_{3}^{-} | Carbonate ion | ||
Methylantmonium ion | CH_{3} NH_{3}^{+} | CH_{3} NH_{2} | Methylamine | ||
Hydrogen phosphate ion | HPO_{4}^{2-} | PO_{4}^{3-} | Phosphate ion | ||
Water | H_{2}O | OH^{-} | Hydroxide ion |
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