Question 12.13: Extrema of Rayleigh Line Consider the T-s diagram of Rayleig...
Extrema of Rayleigh Line
Consider the T-s diagram of Rayleigh flow, as shown in Fig. 12–54. Using the differential forms of the conservation equations and property relations, show that the Mach number is M a_{a}=1 at the point of maximum entropy (point a), M a_{b}=1 / \sqrt{k} and at the point of maximum temperature (point b).

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It is to be shown that M a_{a}=1 at the point of maximum entropy and Ma _{b}=1 / \sqrt{k} at the point of maximum temperature on the Rayleigh line.
Assumptions The assumptions associated with Rayleigh flow (i.e., steady one-dimensional flow of an ideal gas with constant properties through a constant cross-sectional area duct with negligible frictional effects) are valid.
Analysis The differential forms of the continuity (ρV = constant), momentum [rearranged as P + (ρV)V = constant], ideal gas (P = ρRT), and enthalpy change \left(\Delta h=c_{p} \Delta T\right) equations can be expressed as
\rho V=\text { constant } \rightarrow \rho d V+V d \rho=0 \quad \rightarrow \quad \frac{d \rho}{\rho}=-\frac{d V}{V} (1)
P+(\rho V) V=\text { constant } \quad \rightarrow \quad d P+(\rho V) d V=0 \quad \rightarrow \quad \frac{d P}{d V}=-\rho V (2)
P=\rho R T \quad \rightarrow \quad d P=\rho R d T+R T d \rho \quad \rightarrow \quad \frac{d P}{P}=\frac{d T}{T}+\frac{d \rho}{\rho} (3)
The differential form of the entropy change relation (Eq. 12–40) of an ideal gas with constant specific heats is
d s=c_{p} \frac{d T}{T}-R \frac{d P}{P} (4)
s_{2}-s_{1}=c_{P} \ln \frac{T_{2}}{T_{1}}-R \ln \frac{P_{2}}{P_{1}} (12–40)
Substituting Eq. 3 into Eq. 4 gives
d s=c_{p} \frac{d T}{T}-R\left(\frac{d T}{T}+\frac{d \rho}{\rho}\right)=\left(c_{p}-R\right) \frac{d T}{T}-R \frac{d \rho}{\rho}=\frac{R}{k-1} \frac{d T}{T}-R \frac{d \rho}{\rho} (5)
since
c_{p}-R=c_{v} \rightarrow \quad k c_{v}-R=c_{v} \rightarrow \quad c_{v}=R /(k-1)
Dividing both sides of Eq. 5 by dT and combining with Eq. 1,
\frac{d s}{d T}=\frac{R}{T(k-1)}+\frac{R}{V} \frac{d V}{d T} (6)
Dividing Eq. 3 by dV and combining it with Eqs. 1 and 2 give, after rearranging,
\frac{d T}{d V}=\frac{T}{V}-\frac{V}{R} (7)
Substituting Eq. 7 into Eq. 6 and rearranging,
\frac{d s}{d T}=\frac{R}{T(k-1)}+\frac{R}{T-V^{2} / R}=\frac{R\left(k R T-V^{2}\right)}{T(k-1)\left(R T-V^{2}\right)} (8)
Setting ds/dT = 0 and solving the resulting equation R(kRT – V²) = 0 for V give the velocity at point a to be
V_{a}=\sqrt{k R T_{a}} \quad \text { and } \quad Ma _{a}=\frac{V_{a}}{c_{a}}=\frac{\sqrt{k R T_{a}}}{\sqrt{k R T_{a}}}=1 (9)
Therefore, sonic conditions exist at point a, and thus the Mach number is 1.
Setting d T / d s=(d s / d T)^{-1}=0 and solving the resulting equation T(k – 1) × (RT – V²) = 0 for velocity at point b give
V_{b}=\sqrt{R T_{b}} \quad \text { and } \quad Ma _{b}=\frac{V_{b}}{c_{b}}=\frac{\sqrt{R T_{b}}}{\sqrt{k R T_{b}}}=\frac{1}{\sqrt{k}} (10)
Therefore, the Mach number at point b is M a_{b}=1 / \sqrt{k} . For air, k = 1.4 and thus Ma _{b}=0.845 .
Discussion Note that in Rayleigh flow, sonic conditions are reached as the entropy reaches its maximum value, and maximum temperature occurs during subsonic flow.