Question 22.9: High- and Low-Spin Octahedral Complexes How many unpaired e...
High- and Low-Spin Octahedral Complexes
How many unpaired electrons are there in the complex ion [CoF_6]^{3-}?
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Begin by determining the charge and number of d electrons on the metal.
The metal is Co^{3+} and has a d^6 electronic configuration.
Look at the spectrochemical series to determine whether the ligand is a strong-field or a weak-field ligand.
F^- is a weak-field ligand, so ∆ is relatively small.
Decide if the complex is high- or low-spin and draw the electron configuration.
Weak-field ligands yield high-spin configurations.
Count the unpaired electrons.
This configuration has four unpaired electrons.
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