Question 11.10: Hydration Draw the condensed structural formula for the prod...

Hydration

Draw the condensed structural formula for the product that forms in the following hydration reaction:

CH_{3}-CH_{2}-CH_{2}-CH=CH_{2}+HOH \stackrel{H^{+}}{\longrightarrow}
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Reactant Type of Reaction Product
ANALYZE THE
PROBLEM
alkane hydration (asymmetrical alcohol
 double bond)

The H— and —OH from water (H—OH) add to the carbon atoms in the double bond. The H— adds to the carbon with the greater number of hydrogen atoms, and the —OH bonds to the carbon with fewer H atoms.

\begin{array}{r c}\begin{matrix}  \quad \quad \quad \quad \quad \quad \quad \quad \quad{\underset{\downarrow }{{OH}}} \quad \quad {\underset{\downarrow }{{H}}} \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad {\underset{|}{{OH}}} \\ \quad \quad \quad CH_{3}-CH_{2}-CH_{2}-CH=CH_{2}\stackrel{H^{+}}{\longrightarrow} CH_{3}-CH_{2}-CH_{2}-CH-CH_{3} \end{matrix}\end{array}

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