Question 10.3: IDENTIFYING INTERMOLECULAR FORCES Identify the likely kinds ...

IDENTIFYING INTERMOLECULAR FORCES

Identify the likely kinds of intermolecular forces in the following substances:

(a) HCl                        (b) CH_{3}CH_{3}                    (c) CH_{3}NH_{2}             (d) Kr

STRATEGY
Look at the structure of each substance, and decide what intermolecular forces are present. All molecules have dispersion forces; polar molecules have dipole–dipole forces; and molecules with O–H, N–H, or F–H bonds have hydrogen bonds.

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(a) HCl is a polar molecule but can’t form hydrogen bonds. It has dipole–dipole forces and dispersion forces.
(b) CH_{3}CH_{3} is a nonpolar molecule and has only dispersion forces.
(c) CH_{3}NH_{2} is a polar molecule that can form hydrogen bonds. In addition, it has dipole–dipole forces and dispersion forces.
(d) Kr is nonpolar and has only dispersion forces.

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