Question 8.3: Identifying Orbital Overlap in tetrahedral Geometry Identify...
Identifying Orbital Overlap in Tetrahedral Geometry
Identify the orbitals that overlap to form the P-Cl bond in PCl_{3}
STRATEGY
Write the electron-dot structure for PCl_{3} and determine the geometry and hybrid orbitals around the central atom. Determine which orbitals on the terminal atoms are singly occupied and overlap them with the singly occupied hybrid orbitals on the central atom to form a bond.
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The electron-dot structure for PCl_{3} has three single bonds and one lone pair of electrons. There are four charge clouds in a tetrahedral arrangement that corresponds to sp^{3} hybrid orbitals. The shape of PCl_{3} is trigonal pyramidal because there are three bonds and one lone pair.


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