Question 11.12: If 16.3 mL of a 0.185 M Sr(OH)2 solution is used to titrate ...

If 16.3 mL of a 0.185 M Sr(OH)_{2} solution is used to titrate the HCl in a 25.0-mL (0.0250 L) sample of gastric juice, what is the molarity of the HCl solution ?

2HCl(aq) + Sr(OH)_{2}(aq) → 2H_{2}O(l) + SrCl_{2}(aq)
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STEP 1  State the given and needed quantities and concentrations.

ANALYZE THE PROBLEM Given Need Connect
2S.O ml (0.0250 L) of HCI solution, 16.3 ml of 0.18S M Sr(OH)_{2} solution molarity of the HCl solution molarity, mole-mole factor
Neutralization Equation
2HCl(aq) + Sr(OH)_{2}(aq) → 2H_{2}O(l) + SrCl_{2}(aq)

STEP 2  Write a plan to calculate the molarity.

\begin{array}{l}mL  of  Sr(OH)_{2} \\\text{solution}\end{array}    \boxed{\begin{array}{l} \text{Metric}\\\text{factor}\end{array}} →     \begin{array}{l}L  of  Sr(OH)_{2} \\\text{solution}\end{array}      \boxed{Molarity}→    \begin{array}{l} moles  of \\ Sr(OH)_{2}\end{array}     \boxed{\begin{array}{l} \text{Mole-mole}\\\text{factor}\end{array}}→    \begin{array}{l} moles  of\\\text{HCl}\end{array}    \boxed{\begin{array}{l} \text{Divide  by}\\\text{liters}\end{array}}→    \begin{array}{l} \text{molarity  of }\\\text{HCl  solution}\end{array}     

STEP 3  State equalities and conversion factors, including concentrations.

\begin{array}{r c}\boxed{\begin{matrix} 1000  mL  of  Sr(OH)_{2}  solution = 1  L  of  Sr(OH)_{2}  solution \\\frac{1000  mL  Sr(OH)_{2}  solution}{1  L  Sr(OH)_{2}  solution} \text{ and } \frac{1  L  Sr(OH)_{2}  solution}{1000  mL  Sr(OH)_{2}  solution} \end{matrix}} & \boxed{\begin{matrix} 0. 185  mole  of  Sr(OH)_{2} =  1  L  of  Sr(OH)_{2}  solution\\ \frac{0. 185  mole  Sr(OH)_{2}}{ 1  L  Sr(OH)_{2}  solution}\text{ and }\frac{ 1  L  Sr(OH)_{2}  solution}{0. 185  mole  Sr(OH)_{2}} \end{matrix}}\end{array} \begin{array}{r c}\boxed{\begin{matrix} 2  moles  of  HCl = 1  mole  of  Sr(OH)_{2} \\\frac{2  moles  HCl}{1  mole  Sr(OH)_{2}} \text{ and } \frac{1  mole  Sr(OH)_{2}}{2  moles  HCl} \end{matrix}} \end{array}

STEP 4  Set up the problem to calculate the needed quantity. 

16.3  \cancel{mL  Sr(OH)_{2}  solution} \times \boxed{\frac{1  \cancel{L  Sr(OH)_{2}  solution}}{1000  \cancel{mL  Sr(OH)_{2}  solution}}} \times \boxed{\frac{0.185  \cancel{mole  Sr(OH)_{2}}}{1  \cancel{L  Sr(OH)_{2}  solution}}} \times \boxed{\frac{2  moles  HCl}{1  \cancel{mole  Sr(OH)_{2}}}} = 0.00603  mole  of  HCl

 

molarity  of  HCl  solution = \frac{0.00603  mole  HCl }{\boxed{0.0250  L  HCl  solution }} = 0.241  M  HCl  solution

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