Question 7.8: NEARLY DEBYE RELAXATION There are some dielectric solids tha...
NEARLY DEBYE RELAXATION There are some dielectric solids that exhibit nearly Debye relaxation. One example is the La0.7Sr0.3MnO3 ceramic whose relaxation peak and Cole–Cole plots are similar to those shown in Figures 7.13b and 7.17,10especially in the high-frequency range past the resonance peak. La0.7Sr0.3MnO3’s low frequency (εrdc) and high frequency (εr∞) dielectric constants are 3.6 and 2.58, respectively, where low and high refer, respectively, to frequencies far below and above the Debye relaxation peak, i.e.,εrdc and εr∞. The Debye loss peak occurs at 6 kHz. Calculate εr′ and the dielectric loss factor tan δ at 29 kHz.
10 Z. C. Xia et al., J Phys Cond Matter, 13, 4359, 2001. The origin of the dipolar activity in this ceramic is quite complex and involves an electron hopping (jumping) from a Mn3+ to Mn4+ ion; we do not need the physical details in the example.


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The loss peak occurs when ωo=1/τ, so that τ=1/ωo=1/(2π6000)=26.5μs. We can now calculate the real and imaginary parts of εr at 29 kHz,
εr′=εr∞+1+(ωτ)2εrdc−εr∞=2.58+1+[(2π)(29×103)(26.5×10−6)]23.6−2.58=2.62
εr′′=1+(ωτ)2(εrdc−εr∞0)(ωτ)=1+[(2π)(29×103)(26.5×10−6)]2(3.6−2.58)[(2π)(29×103)(26.5×10−6)]=0.202
and hence
tanδ=εr′εr′′=2.620.202=0.077
which is close to the experimental value of 0.084.
This example was a special case of nearly Debye relaxation. Debye equations have been modified over the years to account for the broad relaxation peaks that have been observed, particularly in polymers, by writing the complex εr as
εr=εr∞+[1+(jωτ)α]βεrdc−εr∞ [7.36]
where α and β are constants, typically less than unity (setting α = β = 1 generates the Debye equations). Such equations are useful in engineering for predicting εr at any frequency from a few known values at various frequencies, as highlighted in this simple nearly Debye example. Further, if τ dependence on the temperature T is known (often τ is thermally activated), then we can predict εr at any ω and T.