Question 6.5: Problem: An insulated cylinder fitted with a piston contains...
Problem: An insulated cylinder fitted with a piston contains 5 kg of air at 500 kPa and 1000 K. The air expands in an adiabatic process until its volume doubles. Calculate the work done by the air.
Find: Work W done by air during expansion.
Known: Mass of air m = 5 kg, initial pressure P1 = 500 kPa, initial temperature T1 = 1000 K, final volume ν2=2ν1 , adiabatic process so Q12 = 0.
Assumptions: Air is an ideal gas with constant specific heats, the process is reversible and adiabatic so ∆s = 0
Governing equations:
Isentropic process (ideal gas, constant specific heats) T1T2=⎩⎪⎧ν2ν1⎭⎪⎫(γ−1)
First law ΔU=Q12+W12=Q12+mcν(T2−T1)
Properties: Air at 1000 K has specific heat cν = 0.855 kJ / kgK (Appendix 4), specific heat ratio of air at 1000 K γ = 1.336 (Appendix 4).
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Solving for the final temperature,
T2=T1⎩⎪⎧ν2ν1⎭⎪⎫(γ−1)=1000 K⎩⎪⎧21⎭⎪⎫(1.336−1)=792.235 K.
For an adiabatic process Q12 = 0, so the first law reduces to
W12=mcν(T2−T1)=5 kg×0.855 kJ/kgK×(792.235 K−1000 K)=−888.195 kJ.
Answer: The gas does 888.2 kJ of work on the surroundings.