Question 18.3: Sample Exercise: Energy Levels in a Hydrogen Atom Using the ...

Sample Exercise: Energy Levels in a Hydrogen Atom
Using the energy values shown in figure 18.20, calculate the wavelength of the photon emitted in the transition from the n = 4 energy level to the n = 2 energy level in the Bohr model of the hydrogen atom.

E_{2} = -3.4 eV
E_{4} = -0.85 eV
λ = ?

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The energy difference is

ΔE = E_{4} – E_{2}
= -0.85 eV – (-3.4 eV)
= 2.55 eV
Using h = 6.626 × 10^{-34} J·s = 4.14 × 10^{-15} eV·s,
the frequency of the emitted photon is given by
E = hf

f=\frac{E}{h}

 

f=\frac{2.55  eV}{4.14 × 10^{-15}  eV.s}

 

= 6.16 × 10^{14} Hz

From v = c = fλ, the wavelength of the emitted photon is then

λ=\frac{c}{f}

 

=\frac{3 × 10^{8}  m/s}{6.16 × 10^{14}  Hz}

 

=4.87 × 10^{-7}  m= 487  nm

This is the blue line in the Balmer series of the hydrogen spectrum, pictured in figure 18.17.

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