Question 18.2: Sample Exercise: Using the Rydberg Formula What is the wavel...

Sample Exercise: Using the Rydberg Formula
What is the wavelength of the photon in the infrared series of the hydrogen spectrum for m = 6 and n = 3? Use the Rydberg formula.

R = 1.097 × 10^{7}  m^{-1}

m = 6

n = 3

λ = ?

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\frac{1}{λ}= R (\frac{1}{n^{2}}-\frac{1}{m^{2}})

 

= 1.097 × 10^{7}  m^{-1}(\frac{1}{3^{2}}-\frac{1}{6^{2}})

 

= 1.097 × 10^{7}  m^{-1}(\frac{1}{9}-\frac{1}{36})

 

= 1.097 × 10^{7}  m^{-1}(0.0833)

 

\frac{1}{λ}= 9.14 × 10^{5}  m^{-1}

 

λ= \frac{1}{9.14 × 10^{5}  m^{-1}}= 10.94 × 10^{-7}  m

Notice that this result is in the infrared region of the electromagnetic spectrum because its wavelength is greater than 7.5 × 10^{–7} m, as discussed on page 334 in Chapter 16. Notice also that the m appearing in the Rydberg formula is an integer and has nothing to do with the unit m–1, which is an inverse meter.

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