Question 9.14: The normal concentration of Ca^2+ in blood is 5.0 mEq/L. How...

The normal concentration of Ca^{2+} in blood is 5.0 mEq/L. How many milligrams of Ca^{2+} are in 1.00 L of blood?
ANALYSIS We are given a volume and a concentration in milliequivalents per liter, and we need to find an amount in milligrams. Thus, we need to calculate the gram-equivalent for Ca^{2+} and then use concentration as a conversion factor between volume and mass, as indicated in the following flow diagram:
BALLPARK ESTIMATE The molar mass of calcium is 40.08 g/mol, and the calcium ion carries a charge of 2+ . Thus, 1 g-Eq of Ca^{2+} equals about 20 g/Eq or 20 mg/mEq. This means that the 5.0 mEq of Ca^{2+} ions in 1.00 L of blood corresponds to a mass of 5.0 mEq Ca^{2+} \times 20  mg/mEq = 100  mg  Ca^{2+}.

9.14
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(1.00  \cancel{L  blood}) \left(\frac{5.0  \cancel{mEq  Ca^{2+}}}{1.0  \cancel{L  blood}} \right)\left(\frac{20.04  mg  Ca^{2+}}{1  \cancel{mEq  Ca^{2+}}} \right) = 100  mg  Ca^{2+}

BALLPARK CHECK: The calculated answer (100 mg of Ca^{2+} in 1.00 L of blood) matches our estimate.

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