Question 6.15: Using electronegativity values, classify the bond between ea...

Using electronegativity values, classify the bond between each of the following pairs of atoms as nonpolar covalent, polar covalent, or ionic and label any polar covalent bond with δ^{+}  and  δ^{-} and show the direction of the dipole:

a.  K and O                                                                           b.  As and Cl

c.  N and N                                                                          d.  P and Br

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ANALYZE THE PROBLEM Given Need Connect
pairs of atoms type of bond electronegativity values

For each pair of atoms, we obtain the electronegativity values and calculate the difference in electronegativity.

Atoms Electronegativity Difference Type of Bond Dipole
a.  K and O 3.5 – 0.8 = 2.7 Ionic
b.  As and Cl 3.0 – 2.0 = 1.0 Polar covalent \underset{\longleftrightarrow }{As^{\delta ^{+}}  —  Cl^{\delta ^{-}}}
c. N and N 3.0 – 3.0 = 0.0 Nonpolar covalent
d. P and Br 2.8 – 2.1 = 0.7 Polar covalent \underset{\longleftrightarrow }{P^{\delta ^{+}}  —  Br^{\delta ^{-}}}

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