Question 8.8: USING STANDARD HEATS OF FORMATION TO CALCULATE ΔH° Calculate...
USING STANDARD HEATS OF FORMATION TO CALCULATE ΔH°
Calculate ΔH° in kilojoules for the synthesis of lime (CaO) from limestone (CaCO_{3}), the key step in the manufacture of cement.
CaCO_{3}(s) → CaO(s) + CO_{2}(g) ΔH°_{f} [CaCO_{3}(s)] = -1207.6 kJ/mol
ΔH°_{f}[CaO(s)] = -634.9 kJ/mol
ΔH°_{f} [CO_{2}(g)] = -393.5 kJ/mol
STRATEGY
Subtract the heat of formation of the reactant from the sum of the heats of formation of the products.
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ΔH° = [ΔH°_{f} (CaO) + ΔH°_{f} (CO_{2})] – [ΔH°_{f} (CaCO_{3})]
= (1 mol)(-634.9 kJ/mol) + (1 mol)(-393.5 kJ/mol) – (1 mol)(-1207.6 kJ/mol)
= 179.2 kJ
The reaction is endothermic by 179.2 kJ.
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