Question 10.16: What is the normality of a solution made by diluting 6.5 g o...

What is the normality of a solution made by diluting 6.5 g of H_2SO_4 to a volume of 200 mL? What is the concentration of this solution in milliequivalents per liter? The molar mass of H_2SO_4 is 98.0 g.
ANALYSIS Calculate how many equivalents of H_2SO_4 are in 6.5 g by using the molar mass of the acid as a conversion factor and then determine the normality of the acid.

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STEP 1: Identify known information. We know the molar mass of H_2SO_4, the mass of H_2SO_4 to be dissolved, and the final volume of solution.

MW of H_2SO_4 = 98.0 g/mol
Mass of H_2SO_4 = 6.5 g
Volume of solution = 200 mL

STEP 2: Identify answer including units. We need to calculate the normality of the final solution.

Normality = ?? (equiv./L)

STEP 3: Identify conversion factors. We will need to convert the mass of H_2SO_4 to moles, and then to equivalents of H_2SO_4. We will then need to convert volume from mL to L.

(6.5  \cancel{g  H_2SO_4}) \left(\frac{1  \cancel{mol  H_2SO_4}}{98.0  \cancel{g  H_2SO_4}} \right) \left(\frac{2  Eq  H_2SO_4}{ 1  \cancel{mol  H_2SO_4}} \right) \\ = 0.132 Eq  H_2SO_4  (don't  round  yet!) \\ (200  \cancel{mL}) \left(\frac{1  L}{1000  \cancel{mL}} \right) = 0.200  L

STEP 4: Solve. Dividing the number of equivalents by the volume yields the Normality.

\frac{0.132  Eq  H_2SO_4}{0.200  L } = 0.66  N

The concentration of the sulfuric acid solution is 0.66 N, or 660 mEq/L.

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