Question 9.4: Write the Lewis structure for CO2.

Write the Lewis structure for CO_{2}.

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Because carbon is the less electronegative atom, put it in the central position.
O C O

Total number of electrons for Lewis structure =

\left( \begin{matrix} \text{number of} \\ \text{valence} \\ e^- \text{for }C  \end{matrix} \right) +2 \left( \begin{matrix} \text{number of } \\ \text{valence }\\ e^- \text{for } O \end{matrix}\right)

= 4 + 2(6) = 16

Bonding electrons are first.
O:C:O
(4 of 16 electrons used) Lone pairs on terminal atoms are next.

:\overset{..}{\underset{..}{O}}:C:\overset{..}{\underset{..}{O}}:

(16 of 16 electrons used)

Carbon lacks an octet in this case. Move lone pairs from the oxygen atoms to bonding regions to form double bonds.

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