Question 4.11: WRITING HALF-REACTIONS Write unbalanced half-reactions for t...
WRITING HALF-REACTIONS
Write unbalanced half-reactions for the following net ionic equations:
(a) Mn^{2+}(aq) + ClO_{3}^{-}(aq) → MnO_{2}(s) + ClO_{2}(aq)
(b) Cr_{2}O_{7}^{2-}(aq) + Fe^{2+}(aq) → Cr^{3+}(aq) + Fe^{3+}(aq)
STRATEGY
Look at each equation to see which atoms are being oxidized (increasing in oxidation number) and which are being reduced (decreasing in oxidation number).
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(a) Oxidation: Mn^{+2}(aq) → MnO_{2}(s) Mn goes from +2 to +4
Reduction: ClO_{3}^{-}(aq) → ClO_{2}(aq) Cl goes from +5 to +4
(b) Oxidation: Fe^{2+}(aq) → Fe^{3+}(aq) Fe goes from +2 to +3
Reduction: Cr_{2}O_{7}^{2-}(aq) → Cr^{3+}(aq) Cr goes from +6 to +3
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